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Two New Bismuth Salts with Succinic Acid: Synthesis, Structural, Spectroscopic and Thermal Characterization Научная публикация

Журнал Acta Crystallographica Section C
, E-ISSN: 2053-2296
Вых. Данные Год: 2023, Том: 79, Номер: 10, Страницы: 409-416 Страниц : 8 DOI: 10.1107/s2053229623008124
Ключевые слова bis­muth com­pound; crystal structure; succinic acid; active pharmaceutical ingredient; API; IR spectroscopy; Raman spectroscopy; thermal analysis.
Авторы Timakova Evgeniya V. 1,2 , Afonina L.I. 1,2 , Drebushchak T.N. 1 , Zakharov Boris A. 3,4
Организации
1 Institute of Solid State Chemistry and Mechanochemistry, SB RAS, Kutateladze 18, Novosibirsk 630128, Russian Federation
2 Novosibirsk State Technical University, Prospekt K. Marksa 20, Novosibirsk, 630073, Russian Federation
3 Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation
4 Boreskov Institute of Catalysis, SB RAS, Lavrentieva Avenue 5, Novosibirsk 630090, Russian Federation

Информация о финансировании (2)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) 0239-2021-0002
2 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) 075-00521-21-00 (121032500064-8) (FWUS-2021-0009)

Реферат: Two novel bis­muth succinate hydrates, namely, poly[[di­aqua­(μ3-butane-1,4-di­carboxyl­ato)hemi(μ-butane-1,4-di­carboxyl­ato)bis­muth] monohydrate], {[Bi(C4H4O4)1.5(H2O)2]·H2O}n (1), and poly[[μ-aqua-aqua­(μ3-butane-1,4-di­car­box­yl­ato)(μ-butane-1,4-di­carboxyl­ato)-μ-oxido-dibismuth] monohydrate], {[Bi2(C4H4O4)2O(H2O)2]·H2O}n (2), have been synthesized. Their crystal structures were determined by single-crystal X-ray diffraction and the compounds were characterized by IR and Raman spectroscopy, powder X-ray diffraction and thermal analysis. The crystal structure analysis revealed that the com­pounds are coordination polymers, with 1 having a two-dimensional layered structure and 2 displaying a three-dimensional (3D) framework. Fully deprotonated succinate anions (C4H4O42−) in two different conformations (trans and gauche) are included in their com­position. The Bi3+ cations are surrounded by O atoms from the carboxyl­ate groups of succinate anions and aqua ligands. BiO9 coordination polyhedra in 1 are connected in pairs by edges. These pairs are bound together by bridging succinate ligands to form layers. Bis­muth coordination polyhedra of two different types (BiO9 and BiO7) in 2 are connected by edges to form infinite ribbons. Ribbons of polyhedra with bridging succinate ligands form a 3D polymeric structure.
Библиографическая ссылка: Timakova E.V. , Afonina L.I. , Drebushchak T.N. , Zakharov B.A.
Two New Bismuth Salts with Succinic Acid: Synthesis, Structural, Spectroscopic and Thermal Characterization
Acta Crystallographica Section C. 2023. V.79. N10. P.409-416. DOI: 10.1107/s2053229623008124 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Даты:
Поступила в редакцию: 26 янв. 2023 г.
Принята к публикации: 16 сент. 2023 г.
Опубликована online: 21 сент. 2023 г.
Опубликована в печати: 1 окт. 2023 г.
Идентификаторы БД:
Web of science: WOS:001086804800004
Scopus: 2-s2.0-85174535233
РИНЦ: 54905261
Chemical Abstracts: 2023:2059635
PMID (PubMed): 37733617
OpenAlex: W4386911169
Цитирование в БД: Пока нет цитирований
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