Abstract: The development of the component base for the energetic condensed systems (ECS) is aimed at the use of compounds with high values of density and formation enthalpy. New catalysts are needed for regulating the parameters of their combustion, which not only accelerate the oxidation processes by lowering the activation energy barrier, but also minimize its dependence on pressure. At the same time, they should not decrease the energy density of the condensed systems, thus it is appropriate to use stable metal-organic compounds of transition metals, containing energetic organic ligands and anions that play the role of oxidants. The balanced composition of the catalyst will facilitate the formation of nanoparticles of the catalytically active phase in the combustion wave, accelerating the process. However, there is still no unified theory explaining the mechanism of action of these catalysts. In this work we analyzed the main tendencies of the research in the area of the catalysis of the transformations of energetic condensed compounds in the combustion wave and examined the current developments of the fundamental and applied studies on the effect of catalytic additives on the parameters of thermolysis and high-temperature oxidation of energetic compounds, depending on their nature. Using nickel, iron, and copper complexes with energetic ligands as examples, a catalytic effect on the combustion of nitroamine was shown. The authors are grateful to A.A. Paletsky and A.G. Shmakov for their help in the work and discussion of the results.

Cite: Netskina O.V. , Komova O.V. , Dmitruk K.A. , Mukha S.A. , Simonenko V.N.
Catalytic Methods for Controlling the Parameters of Transformations of Energetic Compounds in the Combustion Wave
In compilation Book of Abstracts of the 10th International Seminar on Flame Structure. 10ISFS. – ICKC SB RAS., 2023. – C.63. – ISBN 9785604990032.

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