Zirconium-Allyl Complexes as Resting States in Zirconocene-Catalyzed α-Olefin Polymerization Full article
| Journal |
Macromolecular Rapid Communications
ISSN: 1022-1336 , E-ISSN: 1521-3927 |
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| Output data | Year: 2015, Volume: 36, Pages: 249-253 Pages count : 5 DOI: 10.1002/marc.201400444 | ||||
| Tags | Allyl complexes, Catalysis, Metallocene catalysts, Olefin polymerization, Resting states | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 14-03-91344 |
| 2 | German Research Foundation | Br 510/15-1 |
Abstract:
UV-vis spectroscopic data indicate that zirconocene cations with Zr-bound allylic chain ends are generally formed during olefin polymerization with zirconocene catalysts. The rates and extent of their formation and of their re-conversion to the initial pre-catalyst cations depend on the types of zirconocene complexes and activators used.
Cite:
Babushkin D.E.
, Panchenko V.N.
, Brintzinger H.H.
Zirconium-Allyl Complexes as Resting States in Zirconocene-Catalyzed α-Olefin Polymerization
Macromolecular Rapid Communications. 2015. V.36. P.249-253. DOI: 10.1002/marc.201400444 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Zirconium-Allyl Complexes as Resting States in Zirconocene-Catalyzed α-Olefin Polymerization
Macromolecular Rapid Communications. 2015. V.36. P.249-253. DOI: 10.1002/marc.201400444 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Dates:
| Submitted: | Aug 8, 2014 |
| Accepted: | Sep 5, 2014 |
| Published online: | Oct 30, 2014 |
| Published print: | Jan 1, 2015 |
Identifiers:
| Web of science: | WOS:000347835200017 |
| Scopus: | 2-s2.0-84921026031 |
| Elibrary: | 23964647 |
| Chemical Abstracts: | 2015:85873 |
| Chemical Abstracts (print): | 162:400172 |
| PMID: | 25358835 |
| OpenAlex: | W1996508350 |