DRIFTS and UV–vis DRS Study of Valeric Acid Ketonization Mechanism over ZrO2 in Hydrogen Atmosphere Full article
| Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
||
|---|---|---|---|
| Output data | Year: 2014, Volume: 388-389, Pages: 133-140 Pages count : 8 DOI: 10.1016/j.molcata.2013.11.012 | ||
| Tags | 5-Nonanone, DRIFTS, Ketonization, Mechanism, UV-vis DRS, Valeric acid | ||
| Authors |
|
||
| Affiliations |
|
Funding (2)
| 1 | Russian Foundation for Basic Research | 13-03-00754 |
| 2 | The Ministry of Education and Science of the Russian Federation | 2012-1.5-12-000-1013-002 |
Abstract:
Adsorption of valeric acid and 5-nonanone on zirconia was investigated by DRIFTS and UV–vis DRS methods. Physical adsorbed and chemisorbed acid and ketone species have been found. Based on the experimental data obtained in this work and on DFT calculations reported in the literature two β-ketoacid routes depending on surface carboxylate intermediates were proposed: (i) via interactions of surface monomolecular monodentate valerate with either monomolecular bridging bidentate or chelating bidentate and (ii) via interactions of two monodentates coordinated to the same Zr cation. The relative contribution of each of them in the overall ketone formation over metal oxide surfaces depends on the reaction conditions.
Cite:
Panchenko V.N.
, Zaytseva Y.A.
, Simonov M.N.
, Simakova I.L.
, Paukshtis E.A.
DRIFTS and UV–vis DRS Study of Valeric Acid Ketonization Mechanism over ZrO2 in Hydrogen Atmosphere
Journal of Molecular Catalysis A: Chemical. 2014. V.388-389. P.133-140. DOI: 10.1016/j.molcata.2013.11.012 WOS Scopus РИНЦ ANCAN OpenAlex
DRIFTS and UV–vis DRS Study of Valeric Acid Ketonization Mechanism over ZrO2 in Hydrogen Atmosphere
Journal of Molecular Catalysis A: Chemical. 2014. V.388-389. P.133-140. DOI: 10.1016/j.molcata.2013.11.012 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jun 30, 2013 |
| Accepted: | Nov 11, 2013 |
| Published online: | Nov 18, 2013 |
| Published print: | Jul 1, 2014 |
Identifiers:
| Web of science: | WOS:000337551800015 |
| Scopus: | 2-s2.0-84901200648 |
| Elibrary: | 22095014 |
| Chemical Abstracts: | 2013:1976820 |
| Chemical Abstracts (print): | 161:23878 |
| OpenAlex: | W1967144407 |