Peroxo‐Zr/Hf‐Containing Wells‐Dawson Polyoxometalates for H2O2‐based Homogeneous, Heterogeneous, and Biphasic Oxidation Catalysis Научная публикация
Журнал |
ChemistryEurope
ISSN: 2751-4765 |
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Вых. Данные | Год: 2024, Том: 2, Номер: 1, Номер статьи : e202300066, Страниц : 13 DOI: 10.1002/ceur.202300066, 10.1002/ceur.202300089 | ||||||
Авторы |
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Организации |
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Информация о финансировании (6)
1 | German Research Foundation | KO 2288/31-1 |
2 | German Research Foundation | KO 2288/29-1 |
3 | German Research Foundation | KO 2288/26-1 |
4 | Российский научный фонд | 23-13-00156 |
5 | Jacobs University Bremen | |
6 | Ministry of Science, Technological Development and Innovation (Serbia) | 451-03-47/2023-01/200146 |
Реферат:
Four peroxo-Zr and Hf containing polyanions, [M2(O2)2(X2W17O61)2]16<M-> (X=P, M=ZrIV (ZrP), HfIV (HfP); X=As, M=ZrIV (ZrAs), HfIV (HfAs) were synthesized and structurally characterized. The structures consist of two monolacunary Wells-Dawson ions which are connected head-on via two side-on peroxo bridges. The four new polyanions are solution-stable as shown by 31P NMR, Raman and FT-IR spectroscopic studies. Comparative studies on alcohol oxidation with a solvent- and phase-transfer catalyst-free biphasic oxidative system with homogeneous and supported-catalyst were performed and several noteworthy observations in reactivity and selectivity were observed, such as the highly selective ring-opening oxidation of cyclohexanol to adipic acid. Tetra-n-butylammonium salts of ZrP and HfP were also synthesized to study the catalytic activity of the compounds in the homogenous H2O2-based oxidation of olefins, α,β-unsaturated carbonyl compounds, and thioethers in organic solvent.
Библиографическая ссылка:
Sundar A.
, Maksimchuk N.V.
, Ivanchikova I.D.
, Zalomaeva O.V.
, Bajuk‐Bogdanović D.
, Kholdeeva O.A.
, Ćirić‐Marjanović G.
, Bassil B.S.
, Kortz U.
Peroxo‐Zr/Hf‐Containing Wells‐Dawson Polyoxometalates for H2O2‐based Homogeneous, Heterogeneous, and Biphasic Oxidation Catalysis
ChemistryEurope. 2024. V.2. N1. e202300066 :1-13. DOI: 10.1002/ceur.202300066, 10.1002/ceur.202300089 РИНЦ OpenAlex
Peroxo‐Zr/Hf‐Containing Wells‐Dawson Polyoxometalates for H2O2‐based Homogeneous, Heterogeneous, and Biphasic Oxidation Catalysis
ChemistryEurope. 2024. V.2. N1. e202300066 :1-13. DOI: 10.1002/ceur.202300066, 10.1002/ceur.202300089 РИНЦ OpenAlex
Даты:
Поступила в редакцию: | 9 сент. 2023 г. |
Принята к публикации: | 11 нояб. 2023 г. |
Опубликована online: | 20 дек. 2023 г. |
Опубликована в печати: | 28 янв. 2024 г. |
Идентификаторы БД:
РИНЦ: | 65870915 |
OpenAlex: | W4389995033 |
Цитирование в БД:
Пока нет цитирований