Effect of Water-Soluble Polymers on the Dynamics of Carbon Dioxide Sorption by Lime-Based Sorbents Full article
Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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Output data | Year: 2023, Volume: 15, Number: 4, Pages: 325-332 Pages count : 8 DOI: 10.1134/S2070050423040062 | ||||
Tags | sorbent, soda lime, carbon dioxide, period of protective effect, water-soluble polymer | ||||
Authors |
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Affiliations |
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Funding (2)
1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0010 |
2 | Ministry of Science and Higher Education of the Russian Federation | 0304-2017-0009 |
Abstract:
This study concerns the effect of water-soluble polymers with different structures on the sorption properties of unregenerable lime-based sorbents of carbon dioxide. It is shown that introducing water-soluble polymers into the composition of sorbents can either prolong or shorten the periods of their protective effect. To explain these findings, the porous structure of sorbents is studied, the transport of carbon dioxide is modeled using molecular dynamics, and coefficients of the diffusion of СО2 in water–polymer solutions are calculated. Modelling results correlate with data from sorption experiments: a stronger dynamic sorption capacity is obtained for a sorbent when a water–polymer medium with a greater coefficient of СО2 diffusion is added. These results can be used to optimize systems for separating carbon dioxide from gaseous mixtures and intensify mass transfer in systems for the photo- and electrocatalytic conversion of СО2 into useful products.
Cite:
Derevshchikov V.S.
, Selyutina O.Y.
Effect of Water-Soluble Polymers on the Dynamics of Carbon Dioxide Sorption by Lime-Based Sorbents
Catalysis in Industry. 2023. V.15. N4. P.325-332. DOI: 10.1134/S2070050423040062 WOS Scopus РИНЦ OpenAlex
Effect of Water-Soluble Polymers on the Dynamics of Carbon Dioxide Sorption by Lime-Based Sorbents
Catalysis in Industry. 2023. V.15. N4. P.325-332. DOI: 10.1134/S2070050423040062 WOS Scopus РИНЦ OpenAlex
Original:
Деревщиков В.С.
, Селютина О.Ю.
Влияние водорастворимых полимеров на динамику сорбции диоксида углерода известковыми сорбентами
Катализ в промышленности. 2023. Т.23. №2. С.6-14. DOI: 10.18412/1816-0387-2023-2-6-14 РИНЦ AN OpenAlex
Влияние водорастворимых полимеров на динамику сорбции диоксида углерода известковыми сорбентами
Катализ в промышленности. 2023. Т.23. №2. С.6-14. DOI: 10.18412/1816-0387-2023-2-6-14 РИНЦ AN OpenAlex
Dates:
Submitted: | Apr 19, 2022 |
Accepted: | Oct 6, 2022 |
Published print: | Dec 26, 2023 |
Published online: | Dec 26, 2023 |
Identifiers:
Web of science: | WOS:001130622200001 |
Scopus: | 2-s2.0-85180556435 |
Elibrary: | 62809997 |
OpenAlex: | W4390225070 |
Citing:
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