The Influence of Carbon Nanomaterials on Catalytic Decomposition of Formic Acid Научная публикация
| Журнал |
International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487 |
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| Вых. Данные | Год: 2024, Том: 57, Страницы: 530-539 Страниц : 10 DOI: 10.1016/j.ijhydene.2023.12.299 | ||
| Ключевые слова | Formic acid, Carbon nanotubes, Carbon nanofibers, Acid-base treatments | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | FWUR-2024-0036 |
Реферат:
Experimental studies were focused on decomposition of formic acid over carbon nanofibers (CNF) and carbon nanotubes (CNT) to produce pure hydrogen. These carbon materials were shown to provide decomposition of formic acid to form preferably hydrogen and carbon dioxide. It was established that structural features of carbon nanomaterials affect their activity in the decomposition of formic acid. The specific catalytic activity of CNF (ini) is at least twice as high as that of CNT (ini). The treatment of CNF (NaOH) with an alkali solution of NaOH is shown to improve noticeably both activity and selectivity of the catalytic decomposition of formic acid. The synthesized catalysts were characterized using X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HRTEM) and adsorption. It was shown by XPS that the alkali treatment of CNF results in the appearance of C–O–Na fragments on the carbon surface
Библиографическая ссылка:
Chesnokov V.V.
, Prosvirin I.P.
, Gerasimov E.Y.
, Miliushina A.S.
The Influence of Carbon Nanomaterials on Catalytic Decomposition of Formic Acid
International Journal of Hydrogen Energy. 2024. V.57. P.530-539. DOI: 10.1016/j.ijhydene.2023.12.299 WOS Scopus РИНЦ CAPlus OpenAlex
The Influence of Carbon Nanomaterials on Catalytic Decomposition of Formic Acid
International Journal of Hydrogen Energy. 2024. V.57. P.530-539. DOI: 10.1016/j.ijhydene.2023.12.299 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 23 окт. 2023 г. |
| Принята к публикации: | 31 дек. 2023 г. |
| Опубликована online: | 27 янв. 2024 г. |
| Опубликована в печати: | 29 февр. 2024 г. |
Идентификаторы БД:
| Web of science: | WOS:001164041500001 |
| Scopus: | 2-s2.0-85182282664 |
| РИНЦ: | 65847906 |
| Chemical Abstracts: | 2024:117966 |
| OpenAlex: | W4390767951 |