Unexpected Effect of N-Heterocyclic Carbene on the Catalytic Activity of Palladium Complex in the Cross-Coupling Reaction of K[C6F5BF3] with Aryl Chlorides Full article
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Doklady Chemistry
ISSN: 0012-5008 , E-ISSN: 1608-3113 |
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| Output data | Year: 2023, DOI: 10.1134/S0012500823600979 | ||||
| Tags | cross-coupling, aryl bromides, aryl chlorides, N-heterocyclic carbenes, pentafluorophenyltrifluoroborate, palladium catalyst | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0008 |
Abstract:
In the palladium-catalyzed cross-coupling of potassium pentafluorophenyltrifluoroborate with aryl chlorides in the presence of the precursor of SIMes carbene, the yields of pentafluorobiphenyls decrease, whereas the yield of 2,3,4,5,6-pentafluoro-4'-methylbiphenyl from 4-bromotoluene under the same conditions increases. An explanation for this phenomenon and for the intensification of the side hydrodeboration reaction of the initial borate has been proposed.
Cite:
Adonin N.Y.
, Shabalin A.Y.
, Prikhod’ko S.A.
, Bardin V.V.
Unexpected Effect of N-Heterocyclic Carbene on the Catalytic Activity of Palladium Complex in the Cross-Coupling Reaction of K[C6F5BF3] with Aryl Chlorides
Doklady Chemistry. 2023. DOI: 10.1134/S0012500823600979 WOS Scopus РИНЦ AN OpenAlex
Unexpected Effect of N-Heterocyclic Carbene on the Catalytic Activity of Palladium Complex in the Cross-Coupling Reaction of K[C6F5BF3] with Aryl Chlorides
Doklady Chemistry. 2023. DOI: 10.1134/S0012500823600979 WOS Scopus РИНЦ AN OpenAlex
Original:
Адонин Н.Ю.
, Шабалин А.Ю.
, Приходько С.А.
, Бардин В.В.
Неожиданное влияние N-гетероциклического карбена на каталитическую активность палладиевого комплекса в реакции кросс-сочетания K[C6F5BF3] с арилхлоридами
Доклады Российской академии наук. Химия, науки о материалах (Доклады Академии наук до 2019 года). 2023. Т.513. №1. С.29-33. DOI: 10.31857/S2686953522600829 РИНЦ OpenAlex
Неожиданное влияние N-гетероциклического карбена на каталитическую активность палладиевого комплекса в реакции кросс-сочетания K[C6F5BF3] с арилхлоридами
Доклады Российской академии наук. Химия, науки о материалах (Доклады Академии наук до 2019 года). 2023. Т.513. №1. С.29-33. DOI: 10.31857/S2686953522600829 РИНЦ OpenAlex
Dates:
| Submitted: | Dec 1, 2022 |
| Accepted: | May 4, 2023 |
| Published online: | Jan 20, 2024 |
Identifiers:
| Web of science: | WOS:001171931500004 |
| Scopus: | 2-s2.0-85182692189 |
| Elibrary: | 63299318 |
| Chemical Abstracts: | 2024:183068 |
| OpenAlex: | W4391065940 |
Citing:
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