Structural and Phase Stability of the Pd-Plated Preceramic Paper Derived Ti3(Al, Si)C2 – TiC Composite at Elevated Temperatures: In-Situ X-Ray Diffraction Investigation | Sciact - CRIS-system of Boreskov Institute of Catalysis

Structural and Phase Stability of the Pd-Plated Preceramic Paper Derived Ti3(Al, Si)C2 – TiC Composite at Elevated Temperatures: In-Situ X-Ray Diffraction Investigation Full article

Journal

Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques
ISSN: 1027-4510 , E-ISSN: 1819-7094

Output data

Year: 2023, Volume: 17, Number: Suppl. 1, Pages: S150-S154 Pages count : 5 DOI: 10.1134/S102745102307025X

Tags

MAX-phase, preceramic papers, ceramic composites, phase transition, synchrotron radiation, in situ X-ray diffraction, high-temperature stability, electroless plating, palladium, scanning electron microscopy

Authors

Krotkevich D.G. ¹ , Kashkarov E.B. ¹ , Syrtanov M.S. ¹ , German D.Y. ² , Mishchenko D.D. ³ , Travitzky N. ^1,4

Affiliations

1	School of Nuclear Science and Engineering, National Research Tomsk Polytechnic University, Tomsk, 634050 Russia
2	Research School of Chemistry and Applied Biomedical Sciences, National Research Tomsk Polytechnic University, Tomsk, 634050 Russia
3	Synchrotron Radiation Facility SKIF, Boreskov Institute of Catalysis SB RAS, Koltsovo, 630559 Russia
4	Department of Materials Science, Glass and Ceramics, Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen, 91054 Germany

Structural and phase stability of the Pd-plated Ti3(Al, Si)C2–TiC composite at elevated temperatures was analyzed by the in situ X-ray diffraction method using synchrotron radiation. Porous Ti3(Al, Si)C2–TiC composite was prepared by spark plasma sintering of preceramic paper with 90 wt % of a Ti3(Al, Si)C2 powder filler at 1000°C and 20 MPa. The sintered composite was covered with a Pd film via electroless plating. During in situ investigation, the Pd-plated composite was linearly heated from 25 to 1000°C and annealed for 1 h at a maximum temperature. Structural and phase analysis reveals a formation of new Pd2Si, PdAl, and PdCx phases. It was noted that the newly formed phases began to be formed during heating at ~750°C. Scanning electron microscopy showed that the obtained Ti3AlSiC2–TiC composite had a well-developed porous structure where some pores were filled with Pd. After high-temperature treatment, Pd could be detected at depths up to 5 μm into the Ti3AlSiC2–TiC composite.

Krotkevich D.G. , Kashkarov E.B. , Syrtanov M.S. , German D.Y. , Mishchenko D.D. , Travitzky N.
Structural and Phase Stability of the Pd-Plated Preceramic Paper Derived Ti3(Al, Si)C2 – TiC Composite at Elevated Temperatures: In-Situ X-Ray Diffraction Investigation
Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques. 2023. V.17. NSuppl. 1. P.S150-S154. DOI: 10.1134/S102745102307025X WOS Scopus AN OpenAlex publication_identifier_short.sciact_skif_identifier_type

Submitted:	Apr 20, 2023
Accepted:	Jun 21, 2023

Web of science:	WOS:001176095900049
Scopus:	2-s2.0-85186558070
Chemical Abstracts:	2024:505839
OpenAlex:	W4392410108
publication_identifier.sciact_skif_identifier_type:	1846

Пока нет цитирований