Structural and Catalytic Properties of Binary Alumina‒Amorphous Aluminosilicate Systems Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2023, Volume: 15, Number: 3, Pages: 229–237 Pages count : 9 DOI: 10.1134/S2070050423030030 | ||
| Tags | catalytic cracking, alumina, amorphous aluminosilicate | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0006 |
Abstract:
Amorphous aluminosilicate‒alumina systems are investigated by a set of physicochemical means that includes studying the NMR 27Al spectra of solid samples and the acidity of catalysts via ammonia temperature-programmed desorption, a structural X-ray diffraction study, and a thermogravimetric analysis of samples. Studying the catalytic properties of samples under the conditions of cracking on a model feedstock
of n-dodecane in a mixture with 2-methylthiophene shows that the conversion of feedstock grows in the order 100% Al2O3 (AHO) > 70% Al‒Si + 30% Al2O3 (AHO) > 30% Al‒Si + 70% Al2O3 (AHO) > 100% Al‒Si (where AHO is the aluminum hydroxide of sulfate synthesis, and Al‒Si is an amorphous aluminosilicate). Raising the calcination temperature of samples from 500 to 700°C reduces the conversion of feedstock.
Increasing the contribution from hydrogen transfer reactions leads to an increase improves the selectivity toward hydrogen sulfide and lowers the content of sulfur compounds in the liquid products.
Cite:
Doronin V.P.
, Bobkova T.V.
, Sorokina T.P.
, Potapenko O.V.
, Yurtaeva A.S.
, Leont’eva N.N.
, Gulyaeva T.I.
Structural and Catalytic Properties of Binary Alumina‒Amorphous Aluminosilicate Systems
Catalysis in Industry. 2023. V.15. N3. P.229–237. DOI: 10.1134/S2070050423030030 WOS Scopus РИНЦ OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Structural and Catalytic Properties of Binary Alumina‒Amorphous Aluminosilicate Systems
Catalysis in Industry. 2023. V.15. N3. P.229–237. DOI: 10.1134/S2070050423030030 WOS Scopus РИНЦ OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Original:
Доронин В.П.
, Бобкова Т.В.
, Сорокина Т.П.
, Потапенко О.В.
, Юртаева А.С.
, Леонтьева Н.Н.
, Гуляева Т.И.
Структурные и каталитические свойства бинарных систем оксид алюминия - аморфный алюмосиликат
Катализ в промышленности. 2023. Т.23. №1. С.6-14. DOI: 10.18412/1816-0387-2023-1-6-14 РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Структурные и каталитические свойства бинарных систем оксид алюминия - аморфный алюмосиликат
Катализ в промышленности. 2023. Т.23. №1. С.6-14. DOI: 10.18412/1816-0387-2023-1-6-14 РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Dates:
| Submitted: | Jun 2, 2022 |
| Accepted: | Aug 3, 2022 |
| Published print: | Sep 4, 2023 |
| Published online: | Sep 4, 2023 |
Identifiers:
| Web of science: | WOS:001061937600002 |
| Scopus: | 2-s2.0-85169702792 |
| Elibrary: | 64267816 |
| OpenAlex: | W4386416766 |
| publication_identifier.sciact_ihcp_identifier_type: | 4238 |