Competition Between the Oxygen Evolution Reaction and the Electrooxidation of Alcohols on Heteroatom-functionalized Multi-walled Carbon Nanotubes-supported Ni Oxide Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Competition Between the Oxygen Evolution Reaction and the Electrooxidation of Alcohols on Heteroatom-functionalized Multi-walled Carbon Nanotubes-supported Ni Oxide Catalysts Full article

Journal

Surfaces and Interfaces
ISSN: 2468-0230

Output data

Year: 2024, Volume: 46, Article number : 104026, Pages count : 14 DOI: 10.1016/j.surfin.2024.104026

Tags

DEMS; Alcohol electrooxidation; Oxygen evolution reaction; Nickel oxide; Hybrid water electrolysis; Heteroatom doping

Authors

Morales Eleazar Castañeda ¹ , Kazakova Mariya A. ² , Selyutin Alexander G. ^2,3 , Golubtsov Georgiy V. ² , Morales Dulce M. ¹ , Robledo Arturo Manzo ¹

Affiliations

1	Instituto Politécnico Nacional, Laboratorio de electroquímica y corrosión. Escuela Superior de Ingeniería Química e Industrias Extractivas, Av. Instituto Politécnico Nacional S/N, Unidad Profesional Adolfo López Mateos, CP 07708 CDMX, México
2	Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia
3	Synchrotron radiation facility SKIF, Boreskov Institute of Catalysis SB RAS, Nikol'skiy Prospekt 1, Kol'tsovo, 630559, Russia

Funding (3)

1	National Polytechnic Institute	SIP-20231003
2	National Council of Science and Technology
3	Ministry of Science and Higher Education of the Russian Federation	ГЗ-2024-2028

Hybrid water electrolysis is a prominent route for hydrogen production that circumvents issues related to the oxygen evolution reaction (OER), the anode process in conventional water electrolysis, by integrating an alternative anode reaction. Herein, samples of nickel oxide nanoparticles supported on oxygen and nitrogen-functionalized multi-walled carbon nanotubes were evaluated as electrocatalysts for the OER and the electrooxidation of methanol (MOR), ethanol (EOR) and glycerol (GOR). The trend of overpotentials measured at a current of 0.1 mA was OER > MOR > EOR > GOR, with slightly lower overpotentials observed for the nitrogen-doped sample, which is attributed to differences in nanoparticle size and distribution, support defectiveness, and nitrogen-induced electronic effects. The production of oxygen was monitored by Differential Electrochemical Mass Spectrometry (DEMS), indicating that the competition between OER and alcohol electrooxidation can be modulated by the support properties as well as by the nature and concentration of the alcohol.

Morales E.C. , Kazakova M.A. , Selyutin A.G. , Golubtsov G.V. , Morales D.M. , Robledo A.M.
Competition Between the Oxygen Evolution Reaction and the Electrooxidation of Alcohols on Heteroatom-functionalized Multi-walled Carbon Nanotubes-supported Ni Oxide Catalysts
Surfaces and Interfaces. 2024. V.46. 104026 :1-14. DOI: 10.1016/j.surfin.2024.104026 WOS Scopus РИНЦ ANCAN OpenAlex publication_identifier_short.sciact_skif_identifier_type

Submitted:	Oct 24, 2023
Accepted:	Feb 1, 2024
Published online:	Feb 2, 2024
Published print:	Mar 1, 2024

Web of science:	WOS:001182355700001
Scopus:	2-s2.0-85184581398
Elibrary:	66491633
Chemical Abstracts:	2024:379091
Chemical Abstracts (print):	186:166999
OpenAlex:	W4391487283
publication_identifier.sciact_skif_identifier_type:	2233

DB	Citing
OpenAlex	2
Scopus	4
Web of science	3
Elibrary	2