Base-Free Cascade Glycerol Conversion to Lactic Acid over Pd-Bi Nanoparticles Immobilized in Metal-Organic Framework Zr-UiO-66 Full article
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Output data | Year: 2024, Volume: 674, Article number : 119603, Pages count : 10 DOI: 10.1016/j.apcata.2024.119603 | ||||
| Tags | glycerol oxidation; lactic acid; palladium; bismuth; UiO-66; bifunctional catalyst | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 19-73-30026 (АААА-А19-119052990037-6) |
Abstract:
In the present work, the Pd-Bi nanoparticles combined with catalytically active support based on the Zr-UiO-66 metal-organic framework are prepared and investigated as bifunctional catalysts in the reaction of the base-free cascade glycerol conversion to lactic acid. The obtained materials are characterized by XRD, TEM, TGA, low-temperature N2 adsorption, XRF, and NH3-TPD. The unique structure and tunability of hybrid materials allow obtaining the lactic acid with a 58% selectivity at a 19% glycerol conversion without the addition of any base. The best hybrid catalysts preserve their structure after catalytic runs and can be recycled at least 4 times without leaching of the active component.
Cite:
Ten S.A.
, Kurmanova M.D.
, Kurmanbayeva K.
, Torbina V.V.
, Stonkus O.A.
, Vodyankina O.V.
Base-Free Cascade Glycerol Conversion to Lactic Acid over Pd-Bi Nanoparticles Immobilized in Metal-Organic Framework Zr-UiO-66
Applied Catalysis A: General. 2024. V.674. 119603 :1-10. DOI: 10.1016/j.apcata.2024.119603 WOS Scopus РИНЦ ANCAN OpenAlex
Base-Free Cascade Glycerol Conversion to Lactic Acid over Pd-Bi Nanoparticles Immobilized in Metal-Organic Framework Zr-UiO-66
Applied Catalysis A: General. 2024. V.674. 119603 :1-10. DOI: 10.1016/j.apcata.2024.119603 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 20, 2023 |
| Accepted: | Feb 3, 2024 |
| Published online: | Feb 9, 2024 |
| Published print: | Mar 25, 2024 |
Identifiers:
| Web of science: | WOS:001185069500001 |
| Scopus: | 2-s2.0-85185264661 |
| Elibrary: | 66598769 |
| Chemical Abstracts: | 2024:363484 |
| Chemical Abstracts (print): | 186:81340 |
| OpenAlex: | W4391691940 |