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Photogeneration of Singlet Oxygen on the Surface of TiO2, Doped by Nitrogen and Non-Doped, under UV- and VIS-Irradiation Full article

Journal High Energy Chemistry
ISSN: 0018-1439
Output data Year: 2023, Volume: 57, Number: Suppl 3, Pages: S391–S396 Pages count : 6 DOI: 10.1134/S0018143923090035
Authors Bogomolov A.S. 1 , Demyanenko A.V. 1 , Selishchev D.S. 2 , Kozlov D.V. 2 , Baklanov A.V. 1
Affiliations
1 Voevodsky Institute of Chemical Kinetics and Combustion, Novosibirsk, 630090 Russia
2 Boreskov Institute of Catalysis, Novosibirsk, 630090 Russia

Funding (2)

1 Ministry of Science and Higher Education of the Russian Federation ГЗ-2024-2028
2 Ministry of Science and Higher Education of the Russian Federation FWGF-2021-0005

Abstract: The paper presents the results of investigation of singlet oxygen formation provided by excitation of the photocatalysts titanium dioxide and nitrogen-doped titanium dioxide by UV- (355 nm) and visible (450 nm) radiation. The appearance of luminescence in the near infrared (NIR) region in both cases indicates the photogeneration of singlet oxygen. The observed short lifetime and large bathochromic shift of the luminescence spectrum indicate that the singlet oxygen appears in the adsorbed state. The presence of nitrogen dopant in the nitrogen-doped titanium dioxide sample has no appreciable effect on the quantum yield of singlet oxygen under visible irradiation when compared with the original titanium dioxide without nitrogen.
Cite: Bogomolov A.S. , Demyanenko A.V. , Selishchev D.S. , Kozlov D.V. , Baklanov A.V.
Photogeneration of Singlet Oxygen on the Surface of TiO2, Doped by Nitrogen and Non-Doped, under UV- and VIS-Irradiation
High Energy Chemistry. 2023. V.57. NSuppl 3. P.S391–S396. DOI: 10.1134/S0018143923090035 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Oct 17, 2023
Accepted: Oct 23, 2023
Published print: Dec 1, 2023
Published online: Feb 27, 2024
Identifiers:
Web of science: WOS:001172975600004
Scopus: 2-s2.0-85185956778
Elibrary: 63357557
Chemical Abstracts: 2024:462616
Chemical Abstracts (print): 186:166076
OpenAlex: W4392210289
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