13C MAS NMR Mechanistic Study of Propene Transformation on Silver-Modified ZSM-5 Zeolite in the Presence of Molecular Oxygen Full article
| Journal |
Applied Magnetic Resonance
ISSN: 0937-9347 , E-ISSN: 1613-7507 |
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| Output data | Year: 2024, Volume: 55, Pages: 1263–1274 Pages count : 12 DOI: 10.1007/s00723-024-01652-0 | ||
| Tags | Carbon dioxide; Molecular oxygen; Nuclear magnetic resonance spectroscopy; Oxidation; Reaction intermediates; Silver; Silver compounds; Zeolites | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Science Foundation | 21-73-10013 |
| 2 | Ministry of Science and Higher Education of the Russian Federation | FWUR-2024-0032 |
Abstract:
Silver-modified zeolites have demonstrated promising properties for hydrocarbon feedstock valorization and the oxidation of organic compounds. Within the frame of the scientific interest for selective oxidation of light alkenes on metal-modified zeolites, the transformation of propene on Ag/H-ZSM-5 zeolite in the presence of molecular oxygen has been monitored by 13C (CP) MAS NMR spectroscopy at 296–773 K. Silver-allyl intermediate species have been detected by 13C CP/MAS NMR, indicating that Ag+ sites are involved in propene transformation. It is assumed that oxygen and propene compete for the Ag+ adsorption sites, thus prompting propene adsorption on zeolite Brønsted acid sites (BAS) and its further transformation by oligomerization and conjunct polymerization. Among the products of propene oxidation by molecular oxygen, only carbon dioxide has been detected by 13C MAS NMR, implying high activity of Ag/H-ZSM-5 in alkene total oxidation. It is thus inferred that silver-modified zeolite is not a promising catalyst for propene selective oxidation to propene oxide and carbonyl group containing organics.
Cite:
Lashchinskaya Z.N.
, Gabrienko A.A.
, Toktarev A.V.
, Stepanov A.G.
13C MAS NMR Mechanistic Study of Propene Transformation on Silver-Modified ZSM-5 Zeolite in the Presence of Molecular Oxygen
Applied Magnetic Resonance. 2024. V.55. P.1263–1274. DOI: 10.1007/s00723-024-01652-0 WOS Scopus РИНЦ AN OpenAlex
13C MAS NMR Mechanistic Study of Propene Transformation on Silver-Modified ZSM-5 Zeolite in the Presence of Molecular Oxygen
Applied Magnetic Resonance. 2024. V.55. P.1263–1274. DOI: 10.1007/s00723-024-01652-0 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Feb 20, 2024 |
| Accepted: | Mar 13, 2024 |
| Published online: | Apr 8, 2024 |
| Published print: | Oct 1, 2024 |
Identifiers:
| Web of science: | WOS:001198549800001 |
| Scopus: | 2-s2.0-85189642277 |
| Elibrary: | 66931559 |
| Chemical Abstracts: | 2024:802542 |
| OpenAlex: | W4394581924 |
Citing:
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