Effect of Preparation Conditions of Nanocrystalline Pd/MgO Catalysts on Their Performance in Selective Hydrogenation of Acetylene | Sciact - CRIS-система Института катализа

Effect of Preparation Conditions of Nanocrystalline Pd/MgO Catalysts on Their Performance in Selective Hydrogenation of Acetylene Научная публикация

Журнал

Molecular Catalysis
ISSN: 2468-8231

Вых. Данные

Год: 2024, Том: 560, Номер статьи : 114151, Страниц : 12 DOI: 10.1016/j.mcat.2024.114151

Ключевые слова

Sol-gel synthesis; Magnesium oxide; Aerogels; Xerogels; Palladium nanoparticles; Acetylene hydrogenation

Авторы

Ilyina Ekaterina V. ¹ , Yurpalova Daria V. ² , Shlyapin Dmitry A. ¹ , Veselov Grigory B. ¹ , Shivtsov Danil M. ^1,3 , Stoyanovskii Vladimir O. ¹ , Bukhtiyarov Andrey V. ¹ , Vedyagin Aleksey A. ¹

Организации

1	Boreskov Institute of Catalysis, 5 Lavrentyev Ave., Novosibirsk 630090, Russia
2	Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, 54 Neftezavodskaya Str., Omsk 644040, Russia
3	National Research Novosibirsk State University, 1 Pirogova Str., Novosibirsk 630090, Russia

Информация о финансировании (2)

1	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	FWUR-2024-0034
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	FWUR-2024-0039

In the present work, an alkoxide sol-gel method was applied to prepare Pd/MgO catalysts. The sol-gel procedure was followed by supercritical drying (aerogels) or conventional drying (xerogels) in a furnace. These materials were compared with the impregnated samples. The Pd loading was 1 wt% in all the cases. The as-prepared catalysts were characterized by a set of physicochemical methods. Both the type of the Pd precursor and the preparation route were found to affect the porous structure of the materials as well as the dispersion of the palladium particles and their localization over the MgO support. Both the xerogel and incipient wetness impregnation methods lead to a narrower pore size distribution in comparison to the aerogel technique. The most dispersed particles with an average size of ∼ 2.0–2.2 nm were observed for the samples prepared by xerogel and impregnation methods. In the case of aerogel-prepared samples, metallic palladium particles possess bimodal distribution with average diameters of 4.3 and 8.4 nm. The best catalytic performance in acetylene hydrogenation to ethylene (50 % acetylene conversion at 37 °C with selectivity ∼60 %) was observed for the Pd/MgO catalyst prepared via the aerogel route using [Pd(NH3)4](NO3)2. Compared to other samples, this material is characterized by relatively weak metal-support interactions and the availability of active sites for reactants, which ensures the kinetic mode of the hydrogenation reaction (Ea = 74.9 kJ/mol).

Ilyina E.V. , Yurpalova D.V. , Shlyapin D.A. , Veselov G.B. , Shivtsov D.M. , Stoyanovskii V.O. , Bukhtiyarov A.V. , Vedyagin A.A.
Effect of Preparation Conditions of Nanocrystalline Pd/MgO Catalysts on Their Performance in Selective Hydrogenation of Acetylene
Molecular Catalysis. 2024. V.560. 114151 :1-12. DOI: 10.1016/j.mcat.2024.114151 WOS Scopus РИНЦ CAPlus OpenAlex ЦНХТ ID

Поступила в редакцию:	24 февр. 2024 г.
Принята к публикации:	12 апр. 2024 г.
Опубликована online:	15 апр. 2024 г.
Опубликована в печати:	1 мая 2024 г.

Web of science:	WOS:001230041900001
Scopus:	2-s2.0-85190255362
РИНЦ:	67278701
Chemical Abstracts:	2024:983014
OpenAlex:	W4394834726
ЦНХТ ID:	4342

БД	Цитирований
OpenAlex	3
Scopus	3
Web of science	3
РИНЦ	1