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Controlling the Ratio of the Reactions of Intermolecular Hydrogen Transfer and Cracking on Apparatuses with Fixed and Circulating Catalytic Beds Full article

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2019, Volume: 11, Number: 2, Pages: 154-161 Pages count : 8 DOI: 10.1134/S2070050419020090
Tags catalytic cracking, hydrogen-transfer reactions, circulating catalytic bed, olefins, deuterated hydrocarbons
Authors Potapenko O.V. 1 , Lutchenko A.S. 2 , Doronin V.P. 1 , Sorokina T.P. 1 , Plekhanov M.A. 2 , Gur’evskikh S.Yu. 2 , Khrapov D.V. 2
Affiliations
1 Institute of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, Omsk, Russia
2 AO Gaspromneft–Omsk Oil Refinery, Omsk, Russia

Funding (1)

1 Federal Agency for Scientific Organizations V.46.2.4

Abstract: The effect the main parameters (temperature, pressure, and dilution of the reaction medium with an inert gas) of such catalytic processes as the cracking of vacuum gasoil and the hydrogenless refining and cracking of gasoline fractions have on the ratio of the selectivity of the cracking and intermolecular hydrogentransfer reactions is studied. Control over the ratio of these reactions allows products to be obtained according to the requirements for processing raw materials. An increase in the time of raw material–catalyst contact, a reduction in the degree of diluting the reaction mixture with an inert gas, and a rise in pressure result in greater selectivity for hydrogen-transfer reactions. Experiments are performed on apparatuses with fixed and circulating beds of zeolite-containing catalysts. The transformation of raw materials containing deuterated compounds is investigated
Cite: Potapenko O.V. , Lutchenko A.S. , Doronin V.P. , Sorokina T.P. , Plekhanov M.A. , Gur’evskikh S.Y. , Khrapov D.V.
Controlling the Ratio of the Reactions of Intermolecular Hydrogen Transfer and Cracking on Apparatuses with Fixed and Circulating Catalytic Beds
Catalysis in Industry. 2019. V.11. N2. P.154-161. DOI: 10.1134/S2070050419020090 WOS Scopus РИНЦ OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Original: Потапенко О.В. , Лутченко А.С. , Доронин В.П. , Сорокина Т.П. , Плеханов М.А. , Гурьевских С.Ю. , Храпов Д.В.
Регулирование соотношения вклада реакций крекинга и межмолекулярного переноса водорода в процессе крекинга бензиновых фракций на установках с неподвижным и циркулирующим слоем катализатора
Катализ в промышленности. 2018. Т.18. №6. С.48-54. DOI: 10.184121816-0387-201864854
Dates:
Submitted: Jun 14, 2018
Accepted: Aug 27, 2018
Published print: Apr 1, 2019
Published online: Jun 25, 2019
Identifiers:
Web of science: WOS:000472891400009
Scopus: 2-s2.0-85067918564
Elibrary: 41685930
OpenAlex: W2953813635
publication_identifier.sciact_ihcp_identifier_type: 1247
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Web of science 1
Elibrary 1
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