Реферат: The novelty of the research was that the transformations were carried out in a pulsed mode at small contact times. A rise in temperature increases the amount of activated methane but decreases the H/C ratio in the surface hydrocarbon fragments. The optimal contact time of methane with the catalyst is in the range from 1 to 2.5 s. It provides the required methane activation depth and, which is most important, the optimal H/C ratio in the surface hydrocarbon fragments СНх equal to 3 at./at. An increase in the amount of strong LAS (a.b. at 2200 cm-1 and higher) in the support enhances methane activation at a considerable decrease in the H/C ratio in the surface hydrocarbon fragments, whereas a substantial increase (in the case of Pt/Al2O3-F, up to 150 mol/g) deteriorates the activity toward methane activation and the H/C ratio.

Библиографическая ссылка: Pashkov V.V. , Golinsky D.V. , Vinichenko N.V. , Belyi A.S.
Non-oxidative Activation of Methane Under a Pulsed Mode in the presence of Supported Platinum-Containing Catalysts
AIP Conference Proceedings. 2019. V.2143. 020041 :1-4. DOI: 10.1063/1.5122940 WOS Scopus РИНЦ CAPlus OpenAlex ЦНХТ ID

Даты:

Опубликована online:

16 авг. 2019 г.

Идентификаторы БД:

Web of science:	WOS:000505769900041
Scopus:	2-s2.0-85071255017
РИНЦ:	41658860
Chemical Abstracts:	2019:2069976
OpenAlex:	W2967527393
ЦНХТ ID:	1916

Цитирование в БД: Пока нет цитирований

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