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The effect of fluorine additives into Pt/WO3-ZrO2-Al2O3 catalysts for n-hexane isomerization Научная публикация

Конференция Oil and Gas Engineering
26-29 февр. 2020 , Омск
Журнал AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Вых. Данные Год: 2019, Том: 2141, Номер статьи : 020012, Страниц : 6 DOI: 10.1063/1.5122031
Ключевые слова isomerization, n-hexane, fluorine addition, tungstated zirconia
Авторы Shkurenok V.A. 1 , Smolikov M.D. 1 , Kir’yanov D.I. 1 , Gulyaeva T.I. 1 , Muromtsev I.V. 1 , Belyi A.S. 1
Организации
1 Center of New Chemical Technologies BIC, 54, Neftezavodskaya St., Omsk 644040, Russian Federation

Информация о финансировании (1)

1 Федеральное агентство научных организаций России V.46.2.4

Реферат: The effect of fluorine additives (1.5–3 wt.%) in Pt/WO3-ZrO2-Al2O3 catalysts on n-hexane isomerization was studied. The best performance was obtained in the presence of catalyst with the fluorine content 2.5 wt.% at 240°C: conversion – 80.0 %, selectivity – 88.5%, yield of stable catalyzate – 93.2 wt.%, yield of the sum of hexane isomers – 70.8 wt.%, and yield of high-octane dimethylbutanes (DMB) – 16.1 wt.%. Fluorine additives were shown to change the unit cell parameter a of tetragonal zirconia due to the substitution of oxygen atoms by fluorine atoms.
Библиографическая ссылка: Shkurenok V.A. , Smolikov M.D. , Kir’yanov D.I. , Gulyaeva T.I. , Muromtsev I.V. , Belyi A.S.
The effect of fluorine additives into Pt/WO3-ZrO2-Al2O3 catalysts for n-hexane isomerization
AIP Conference Proceedings. 2019. V.2141. 020012 :1-6. DOI: 10.1063/1.5122031 WOS Scopus РИНЦ CAPlus OpenAlex ЦНХТ ID
Даты:
Опубликована online: 28 авг. 2019 г.
Идентификаторы БД:
Web of science: WOS:000516716100012
Scopus: 2-s2.0-85072120849
РИНЦ: 41674120
Chemical Abstracts: 2019:2098904
OpenAlex: W2971115660
ЦНХТ ID: 1938
Цитирование в БД:
БД Цитирований
Scopus 1
Web of science 1
РИНЦ 2
OpenAlex 1
Альметрики: