A Study on the Effect of Activation Conditions of Pt/Al2O3–BEA Catalyst and Conditions of Benzene Hydroisomerization on the Catalytic Performance | Sciact - CRIS-system of Boreskov Institute of Catalysis

A Study on the Effect of Activation Conditions of Pt/Al2O3–BEA Catalyst and Conditions of Benzene Hydroisomerization on the Catalytic Performance Full article

Conference

Oil and Gas Engineering
26-29 Feb 2020 , Омск

Journal

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Output data

Year: 2019, Number: 2141, Article number : 020021, Pages count : 7 DOI: 10.1063/1.5122040

Authors

Kalashnikov I.M. ^1,2 , Belopukhov E.A. ¹ , Smolikov M.D. ¹ , Kir’yanov D.I. ¹ , Belyi A.S. ¹

Affiliations

1	Center of New Chemical Technologies BIC, 54, Neftezavodskaya str., Omsk 644040, Russia
2	Omsk State Technical University, 11, Mira Pr., Omsk 644050, Russia

Funding (1)

Federal Agency for Scientific Organizations

V.46.2.4

Hydroisomerization of a benzene/heptane mixture over platinum catalysts supported on BEA zeolite with alumina addition was studied. The catalyst activation conditions – temperatures of its oxidative calcination and reduction with hydrogen as well as the conditions of hydroisomerization reaction were examined. It was shown that the catalyst should be reduced in flowing hydrogen at 350oC without precalcination in an air flow. The operating temperature of the process and the catalyst selectivity to target products can be controlled by varying the liquid hourly space velocity. A decrease in the H2/feed ratio to 1/1 mol/mol leads to a substantial drop in the yield of heptanes with isomeric structure and methylcyclopentane.

Kalashnikov I.M. , Belopukhov E.A. , Smolikov M.D. , Kir’yanov D.I. , Belyi A.S.
A Study on the Effect of Activation Conditions of Pt/Al2O3–BEA Catalyst and Conditions of Benzene Hydroisomerization on the Catalytic Performance
AIP Conference Proceedings. 2019. N2141. 020021 :1-7. DOI: 10.1063/1.5122040 WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type

Published online:

Aug 28, 2019

Web of science:	WOS:000516716100021
Scopus:	2-s2.0-85072101610
Elibrary:	41645354
Chemical Abstracts:	2019:2098941
OpenAlex:	W2970396196
publication_identifier.sciact_ihcp_identifier_type:	1946

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