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Comparison of the Activity of Ru-K/Sibunit Catalysts in Ammonia Synthesis and Decomposition Full article

Conference Oil and Gas Engineering
26-29 Feb 2020 , Омск
Journal AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Output data Year: 2019, Volume: 2141, Article number : 020024, Pages count : 7 DOI: 10.1063/1.5122043
Tags low temperature synthesis of ammonia, low temperature decomposition of ammonia, Ru-K/Sibunit, thermal stability of catalysts
Authors Petrunin D.A. 1 , Borisov V.A. 1,2 , Iost K.N. 2 , Temerev V.L. 2 , Trenikhin M.V. 1,2 , Gulyaeva T.I. 2 , Shlyapin D.A. 2 , Tsyrul'nikov P.G. 2
Affiliations
1 Omsk State Technical University, 11, Mira Pr., Omsk 644050, Russia
2 Center of New Chemical Technologies BIC SB RAS, 54, Neftezavodskaya str., Omsk 644040, Russia

Funding (1)

1 Federal Agency for Scientific Organizations V.46.2.5. (АААА-А17-117021450096-8)

Abstract: Ru-K/Sibunit catalysts with different molar ratio of promotor and active component were studied in the low temperature synthesis and decomposition of ammonia. It was shown that activity of the catalysts in the synthesis reaction increases with the molar ratio of potassium and ruthenium: 0.087 and 0.397 mmol NH3/gcat*h for K/Ru = 0.5 and 2.5, respectively, at a temperature of 350 C, whereas in the decomposition reaction the activity decreases and is equal to 349.2 and 73.8 mmol NH3/gcat*h, respectively, for K/Ru = 0.5 and 2.5 at 450 C.
Cite: Petrunin D.A. , Borisov V.A. , Iost K.N. , Temerev V.L. , Trenikhin M.V. , Gulyaeva T.I. , Shlyapin D.A. , Tsyrul'nikov P.G.
Comparison of the Activity of Ru-K/Sibunit Catalysts in Ammonia Synthesis and Decomposition
AIP Conference Proceedings. 2019. V.2141. 020024 :1-7. DOI: 10.1063/1.5122043 WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Dates:
Submitted: Jul 19, 2019
Published online: Aug 28, 2019
Identifiers:
Web of science: WOS:000516716100024
Scopus: 2-s2.0-85072129178
Elibrary: 41674857
Chemical Abstracts: 2019:2098940
OpenAlex: W2970548415
publication_identifier.sciact_ihcp_identifier_type: 1948
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