The Unique Chemistry of 4,5-Dichloro-2-Dichloromethylene-4-Cyclopentene-1,3-Dione and Thiourea | Sciact - CRIS-system of Boreskov Institute of Catalysis

The Unique Chemistry of 4,5-Dichloro-2-Dichloromethylene-4-Cyclopentene-1,3-Dione and Thiourea Full article

Conference

6th All-Russian Scientific School-Conference for Young Scientists on Chemistry under the Sign of SIGMA: Research, Innovation, Technology
18-20 May 2020 , Омск

Journal

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Output data

Year: 2020, Volume: 2301, Article number : 040019, Pages count : 6 DOI: 10.1063/5.0032826

Authors

Talsi V.P. ¹ , Yurpalov V.L. ¹

Affiliations

1	Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, 54, Neftezavodskaya Str., Omsk 644040, Russian Federation

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

0364-2019-0006

The information on the structure of the telomer that was produced by the reaction of thiourea with 4,5-dichloro-2-dichloromethylene-4-cyclopentene-1,3-dione have been refined. Mixing of acetone solutions of 4,5-dichloro2-dichloromethylene-4-cyclopentene-1,3-dione and thiourea leads to immediate and quantitative formation of the telomer precipitate, which is a Möbius aromatic compound in which half of carbon atoms are simultaneously in saturated and unsaturated state due to the involvement of electron-deficient six-electron four-centered (6e – 4c) ı-bonds.

Talsi V.P. , Yurpalov V.L.
The Unique Chemistry of 4,5-Dichloro-2-Dichloromethylene-4-Cyclopentene-1,3-Dione and Thiourea
AIP Conference Proceedings. 2020. V.2301. 040019 :1-6. DOI: 10.1063/5.0032826 Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type

Published online:

Dec 8, 2020

Scopus:	2-s2.0-85098083283
Elibrary:	45063767
Chemical Abstracts:	2021:1128876
OpenAlex:	W3110678228
publication_identifier.sciact_ihcp_identifier_type:	3291

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