Stability of Pd/Sibunit and Pd-M/Sibunit (M: Zn, Ag) Catalysts for Gas-Phase Acetylene Hydrogenation Full article
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6th All-Russian Scientific School-Conference for Young Scientists on Chemistry under the Sign of SIGMA: Research, Innovation, Technology 18-20 May 2020 , Омск |
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AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616 |
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| Output data | Year: 2020, Volume: 2301, Article number : 030005, Pages count : 4 DOI: 10.1063/5.0032868 | ||
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | V.46.2.5. (АААА-А17-117021450096-8) |
Abstract:
Pd/Sibunit and Pd-M/Sibunit (M: Zn, Ag) catalysts were investigated in the selective gas-phase acetylene hydrogenation. It was found that modified Pd-Zn/Sibunit and Pd-Ag/Sibunit catalysts have stable properties for 10 hours at 85°C, while the activity of monometallic Pd/Sibunit sample is gradually decreased from 791 to 717 ml(C2H4)/g•min. Using the DTA method, it was shown that light carbonaceous deposits, based on acetylene oligomerization products, form on the surface of Pd/Sibunit and Pd-M/Sibunit catalysts during the reaction. It was found by the NMR method that the oligomers trapped by Pd/Sibunit surface is C8 hydrocarbons. It is assumed that the differences in the resistance to deactivation of Pd/Sibunit and modified systems can be associated with different localization of carbon deposits on the surface of studied catalysts.
Cite:
Glyzdova D.V.
, Afonasenko T.N.
, Talsi V.P.
, Shlyapin D.A.
Stability of Pd/Sibunit and Pd-M/Sibunit (M: Zn, Ag) Catalysts for Gas-Phase Acetylene Hydrogenation
AIP Conference Proceedings. 2020. V.2301. 030005 :1-4. DOI: 10.1063/5.0032868 Scopus РИНЦ ANCAN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Stability of Pd/Sibunit and Pd-M/Sibunit (M: Zn, Ag) Catalysts for Gas-Phase Acetylene Hydrogenation
AIP Conference Proceedings. 2020. V.2301. 030005 :1-4. DOI: 10.1063/5.0032868 Scopus РИНЦ ANCAN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Dates:
| Published print: | Dec 8, 2020 |
Identifiers:
| Scopus: | 2-s2.0-85098069554 |
| Elibrary: | 45098870 |
| Chemical Abstracts: | 2021:1128897 |
| Chemical Abstracts (print): | 175:131800 |
| OpenAlex: | W3111218201 |
| publication_identifier.sciact_ihcp_identifier_type: | 3294 |