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Influence of Oxidative Treatment and Platinum Content on the Stability of the Pt/Sibunit System in an Oxidizing Atmosphere at Elevated Temperatures Full article

Journal Solid Fuel Chemistry
ISSN: 0361-5219 , E-ISSN: 1934-8029
Output data Year: 2020, Volume: 54, Number: 6, Pages: 385-391 Pages count : 7 DOI: 10.3103/S0361521920060026
Tags carbon; oxidation stability; phase composition; porous structure; Pt/C; Sibunit
Authors Borisov V.A. 1 , Iost K.N. 1 , Temerev V.L. 1 , Simonova A.D. 1 , Belopukhov Е.А. 1 , Sigaeva S.S. 1 , Smorokov А.А. 2 , Trenikhin M.V. 1 , Savel'eva G.G. 1 , Muromtsev I.V. 1 , Osipov A.R. 1 , Shlyapin D.A. 1
Affiliations
1 Center of New Chemical Technologies, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Omsk, 644040 Russia
2 National Research Tomsk Polytechnic University, Tomsk, 634050 Russia

Funding (2)

1 Federal Agency for Scientific Organizations V.46.2.5. (АААА-А17-117021450096-8)
2 Ministry of Science and Higher Education of the Russian Federation Приоритет 2030

Abstract: The effect of elevated temperatures on the textural and structural characteristics of the carbon material Sibunit in an oxygen-containing atmosphere was studied depending on the preliminary treatment of Sibunit with HNO3 and the presence and the amount of an active component (Pt). According to the results of thermogravimetry, the preliminary treatment of Sibunit with HNO3 led to an increase in the temperature range of carbon oxidation, while the introduction of Pt led to a decrease in this temperature range. It was found that an exposure of Pt/Sibunit samples for 4 h in a nitrogen–air mixture at a temperature of 400°C led to an increase in the total volume and average pore diameter with a slight change in the specific surface area, and the average particle size of platinum increased from 2 to 5 nm.
Cite: Borisov V.A. , Iost K.N. , Temerev V.L. , Simonova A.D. , Belopukhov Е.А. , Sigaeva S.S. , Smorokov А.А. , Trenikhin M.V. , Savel'eva G.G. , Muromtsev I.V. , Osipov A.R. , Shlyapin D.A.
Influence of Oxidative Treatment and Platinum Content on the Stability of the Pt/Sibunit System in an Oxidizing Atmosphere at Elevated Temperatures
Solid Fuel Chemistry. 2020. V.54. N6. P.385-391. DOI: 10.3103/S0361521920060026 WOS Scopus РИНЦ AN OpenAlex
Original: Борисов В.А. , Иост К.Н. , Темерев В.Л. , Симонова А.Д. , Белопухов Е.А. , Сигаева С.С. , Смороков А.А. , Тренихин М.В. , Савельева Г.Г. , Муромцев И.В. , Осипов А.Р. , Шляпин Д.А.
Влияние окислительной обработки и содержания платины на устойчивость системы Pt/Сибунит в окислительной атмосфере при повышенной температуре
Химия твердого топлива. 2020. №6. С.46-52. DOI: 10.31857/S002311772006002X РИНЦ publication_identifier_short.sciact_ihcp_identifier_type publication_identifier_short.sciact_ihcp_identifier_type
Dates:
Submitted: Mar 20, 2020
Accepted: Jul 15, 2020
Published print: Nov 1, 2020
Published online: Dec 7, 2020
Identifiers:
Web of science: WOS:000599503000007
Scopus: 2-s2.0-85097624569
Elibrary: 45079936
Chemical Abstracts: 2020:2667512
OpenAlex: W3094036998
Citing:
DB Citing
Scopus 2
Web of science 2
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