Sustainable Hydrogenation of Vinyl Derivatives Using Pd/C Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Sustainable Hydrogenation of Vinyl Derivatives Using Pd/C Catalysts Full article

Journal

Catalysts
ISSN: 2073-4344

Output data

Year: 2021, Volume: 11, Number: 2, Article number : 179, Pages count : 14 DOI: 10.3390/catal11020179

Tags

molecular hydrogen; hydrogenation; Pd/C catalysts; calcium carbide; acetylene; vinyl group

Authors

Mironenko Roman M. ¹ , Saybulina Elina R. ¹ , Stepanova Liudmila N. ¹ , Gulyaeva Tatiana I. ¹ , Trenikhin Mikhail V. ¹ , Rodygin Konstantin S. ² , Ananikov Valentine P. ³

Affiliations

1	Center of New Chemical Technologies BIC, Neftezavodskaya st. 54, 644040 Omsk, Russia
2	Institute of Chemistry, Saint Petersburg State University, Universitetskiy pr. 26, 198504 Saint Petersburg, Russia
3	N. D. Zelinsky Institute of Organic Chemistry, Leninsky pr. 47, 119991 Moscow, Russia

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

0239-2021-0004

The hydrogenation of unsaturated double bonds with molecular hydrogen is an efficient atom-economic approach to the production of a wide range of fine chemicals. In contrast to a number of reducing reagents typically involved in organic synthesis, hydrogenation with H2 is much more sustainable since it does not produce wastes (i.e., reducing reagent residues). However, its full sustainable potential may be achieved only in the case of easily separable catalysts and high reaction selectivity. In this work, various Pd/C catalysts were used for the liquid-phase hydrogenation of O-, S-, and N-vinyl derivatives with molecular hydrogen under mild reaction conditions (room temperature, pressure of 1 MPa). Complete conversion and high hydrogenation selectivity (>99%) were achieved by adjusting the type of Pd/C catalyst. Thus, the proposed procedure can be used as a sustainable method for vinyl group transformation by hydrogenation reactions. The discovery of the stability of active vinyl functional groups conjugated with heteroatoms (O, S, and N) under hydrogenation conditions over Pd/C catalysts opens the way for many useful transformations.

Mironenko R.M. , Saybulina E.R. , Stepanova L.N. , Gulyaeva T.I. , Trenikhin M.V. , Rodygin K.S. , Ananikov V.P.
Sustainable Hydrogenation of Vinyl Derivatives Using Pd/C Catalysts

Catalysts. 2021. V.11. N2. 179 :1-14. DOI: 10.3390/catal11020179 WOS Scopus РИНЦ ANCAN OpenAlex

Full text from publisher

Submitted:	Dec 29, 2020
Accepted:	Jan 26, 2021
Published online:	Jan 28, 2021
Published print:	Feb 1, 2021

Web of science:	WOS:000622256200001
Scopus:	2-s2.0-85099850888
Elibrary:	44988163
Chemical Abstracts:	2021:389241
Chemical Abstracts (print):	174:720785
OpenAlex:	W3127472868

DB	Citing
Scopus	5
Web of science	6
Elibrary	5
OpenAlex	6