Sciact
  • EN
  • RU

Investigation of Fluorine-Promoted Pt-Re/Al2O3 Catalysts in Reforming of n-Heptane Full article

Journal Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Output data Year: 2021, Volume: 378, Pages: 113-118 Pages count : 6 DOI: 10.1016/j.cattod.2021.06.016
Tags n-Heptane, Reforming, Platinum-rhenium alumina, Fluorine promotion, High octane gasoline component
Authors Belopukhov Evgeny A. 1 , Kir'yanov Dmitry I. 1 , Smolikov Mikhail D. 1 , Shkurenok Violetta A. 1 , Belyi Alexander S. 1 , Lavrenov Alexander V. 1 , Kleimenov Andrey V. 2 , Kondrashev Dmitry O. 2
Affiliations
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, 54, Neftezavodskaya str., Omsk 644040, Russia
2 PJSC Gazprom Neft, 3-5 Pochtamtskaya str., Saint-Petersburg 190000, Russia

Funding (1)

1 Газпром нефть 15/08000/ 00132/R/040

Abstract: The effect of fluorine promotion of Pt-Re/Al2O3 catalysts on their acidic and catalytic properties in the reforming of n-heptane was studied. An increase in fluorine content of the catalysts from 0.4 to 2.0 wt% was shown to increase total acidity of the samples mostly due to the medium-strength and strong acid sites. The increase in acidity of the fluorine-containing catalysts was accompanied by an enhancement of their activity toward the transformations of n-heptane. Therewith, the fluorine addition (0.4–2.0 wt%) allowed obtaining the product with a decreased content of aromatic hydrocarbons in the reformate at the retained octane number.
Cite: Belopukhov E.A. , Kir'yanov D.I. , Smolikov M.D. , Shkurenok V.A. , Belyi A.S. , Lavrenov A.V. , Kleimenov A.V. , Kondrashev D.O.
Investigation of Fluorine-Promoted Pt-Re/Al2O3 Catalysts in Reforming of n-Heptane
Catalysis Today. 2021. V.378. P.113-118. DOI: 10.1016/j.cattod.2021.06.016 WOS Scopus РИНЦ ANCAN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Dates:
Submitted: Dec 7, 2020
Accepted: Jun 16, 2021
Published online: Jun 23, 2021
Published print: Oct 15, 2021
Identifiers:
Web of science: WOS:000687204700004
Scopus: 2-s2.0-85108538647
Elibrary: 46842923
Chemical Abstracts: 2021:1586000
Chemical Abstracts (print): 177:224091
OpenAlex: W3176552543
publication_identifier.sciact_ihcp_identifier_type: 3594
Citing:
DB Citing
Web of science 5
Scopus 6
Elibrary 3
OpenAlex 5
Altmetrics: