Synthesis of Nickel–Carbon Nanocomposites Using the Mechanical Treatment of Polyvinyl Chloride in the Presence of Nickel Nitrate and Diethylamine Full article
| Journal |
Solid Fuel Chemistry
ISSN: 0361-5219 , E-ISSN: 1934-8029 |
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| Output data | Year: 2021, Volume: 55, Number: 6, Pages: 374-379 Pages count : 6 DOI: 10.3103/S036152192106015X | ||
| Tags | nanoparticles, nanocomposites, core–shell, carbon shell, metal core, chloropolymers, mechanical activation, nanotubes | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0004 |
Abstract:
The dehydrochlorination of polyvinyl chloride with diethylamine in the presence of nickel nitrate was carried out on mechanical processing in a high-energy planetary mill. The subsequent heat treatment of the resulting product to 400°C led to the formation of a metal–carbon nanocomposite, in which nickel nanoparticles 50–100 nm in diameter were distributed in an amorphous carbon matrix. The nickel–carbon nanocomposite exhibited catalytic activity in the process of methane conversion at 800°C. Deposits of ordered nanosized carbon structures of two types were observed on metal particles: a graphite-like shell containing up to 80 layers with an interlayer distance of 0.36 nm and bamboo-like nanotubes with a diameter of 30–80 nm. The structure of the resulting products was investigated by transmission and scanning electron microscopy
Cite:
Zapevalova E.S.
, Trenikhin M.V.
, Kryazhev Y.G.
Synthesis of Nickel–Carbon Nanocomposites Using the Mechanical Treatment of Polyvinyl Chloride in the Presence of Nickel Nitrate and Diethylamine
Solid Fuel Chemistry. 2021. V.55. N6. P.374-379. DOI: 10.3103/S036152192106015X WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Synthesis of Nickel–Carbon Nanocomposites Using the Mechanical Treatment of Polyvinyl Chloride in the Presence of Nickel Nitrate and Diethylamine
Solid Fuel Chemistry. 2021. V.55. N6. P.374-379. DOI: 10.3103/S036152192106015X WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Original:
Запевалова Е.С.
, Тренихин М.В.
, Кряжев Ю.Г.
Синтез никель-углеродных нанокомпозитов с использованием механообработки поливинилхлорида в присутствии нитрата никеля и диэтиламина
Химия твердого топлива. 2021. №6. С.22-27. DOI: 10.31857/S0023117721060153 РИНЦ OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Синтез никель-углеродных нанокомпозитов с использованием механообработки поливинилхлорида в присутствии нитрата никеля и диэтиламина
Химия твердого топлива. 2021. №6. С.22-27. DOI: 10.31857/S0023117721060153 РИНЦ OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Dates:
| Submitted: | Jun 11, 2021 |
| Accepted: | Jul 21, 2021 |
| Published print: | Nov 1, 2021 |
| Published online: | Dec 8, 2021 |
Identifiers:
| Web of science: | WOS:000728175500003 |
| Scopus: | 2-s2.0-85120846527 |
| Elibrary: | 47538209 |
| Chemical Abstracts: | 2021:2780724 |
| OpenAlex: | W4200144775 |
| publication_identifier.sciact_ihcp_identifier_type: | 3616 |