Bimetallic Ni-Co Catalyst for Improving Selectivity in Transfer Hydrogenation of Phenolic Compounds Full article
| Journal |
Molecular Catalysis
ISSN: 2468-8231 |
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| Output data | Year: 2024, Volume: 561, Article number : 114200, Pages count : 10 DOI: 10.1016/j.mcat.2024.114200 | ||
| Tags | Transfer hydrogenation; Phenolic compounds; 2-PrOH, Ni-Co catalyst; Hydrodeoxygenation | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | FWUR-2024-0032 |
Abstract:
The study investigated the transfer hydrogenation of guaiacol, anisole, phenol, and positional isomers of dimethoxybenezene using 2-PrOH as the H-donor over Ni, Co, and Ni-Co catalysts. The catalysts, which contained 5 wt% metal, were prepared by the deposition-precipitation method. The results showed that the catalysts had developed a pore structure and fine metal particles. The Ni and Ni-Co catalysts demonstrated exceptional activity in the transfer hydrogenation of phenolic compounds with a substrate to metal molar ratio of 100 to 1. Furthermore, the addition of Co to Ni significantly impacted the selectivity of transfer hydrogenation promoting hydrodeoxygenation of anisole and guaiacol.
Cite:
Philippov A.A.
, Nasokhov D.E.
, Prosvirin I.P.
, Martyanov O.N.
Bimetallic Ni-Co Catalyst for Improving Selectivity in Transfer Hydrogenation of Phenolic Compounds
Molecular Catalysis. 2024. V.561. 114200 :1-10. DOI: 10.1016/j.mcat.2024.114200 WOS Scopus РИНЦ AN OpenAlex
Bimetallic Ni-Co Catalyst for Improving Selectivity in Transfer Hydrogenation of Phenolic Compounds
Molecular Catalysis. 2024. V.561. 114200 :1-10. DOI: 10.1016/j.mcat.2024.114200 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Mar 14, 2024 |
| Accepted: | May 2, 2024 |
| Published online: | May 6, 2024 |
| Published print: | May 15, 2024 |
Identifiers:
| Web of science: | WOS:001238898500001 |
| Scopus: | 2-s2.0-85192093550 |
| Elibrary: | 67493926 |
| Chemical Abstracts: | 2024:1386798 |
| OpenAlex: | W4396660892 |
Citing:
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