Sciact
  • EN
  • RU

Turbostratic Carbon Nanofibers Produced from C2HCl3 over Self-Dispersing Ni-Catalyst Doped with W and Mo Научная публикация

Журнал Diamond and Related Materials
ISSN: 0925-9635 , E-ISSN: 1879-0062
Вых. Данные Год: 2024, Том: 148, Номер статьи : 111416, Страниц : 12 DOI: 10.1016/j.diamond.2024.111416
Ключевые слова Trimetallic Ni-Mo-W alloy; Catalytic chemical vapor deposition; Carbon nanofibers; Turbostratic structure; High carbon yield
Авторы Potylitsyna Arina R. 1 , Bauman Yury I. 1 , Ayupov Artem B. 1,2 , Plyusnin Pavel E. 3 , Shubin Yury V. 3 , Stoyanovskii Vladimir O. 1 , Vedyagin Aleksey A. 1 , Mel'gunov Maksim S. 1 , Korenev Sergey V. 3 , Mishakov Ilya V. 1
Организации
1 Boreskov Institute of Catalysis, pr. Ac. Lavrentieva, 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, str. Pirogova 2, Novosibirsk 630090, Russia
3 Nikolaev Institute of Inorganic Chemistry, Ac. Lavrentieva 3, Novosibirsk 630090, Russia

Информация о финансировании (2)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) FWUR-2024-0034
2 Министерство образования и науки Российской Федерации FWUZ-2021-0002 (121031700315-2)

Реферат: In this research, a self-dispersing 92Ni-4Mo-4 W catalyst showing high productivity towards the H2-assisted synthesis of turbostratic carbon nanofibers was proposed. The effect of reaction temperature on the efficiency of 92Ni-4Mo-4 W alloy in the decomposition of trichloroethylene was studied. It was found that in the temperature range of 580–620 °C, the most rapid destruction of the initial alloy followed by the growth of carbon material is realized. This is confirmed by the minimum induction period (9–11 min) and the maximum carbon yield (95–107 g/gcat). As revealed, the catalytically active particles of submicron size contain uniformly distributed Ni, Mo, and W. It is demonstrated that the decomposition of trichloroethylene over the 92Ni-4Mo-4 W catalyst results in the formation of a turbostratic carbon material with a segmented structure, containing a minimum quantity of amorphous carbon and possessing high textural characteristics (specific surface area of 330–410 m2/g; pore volume of 0.48–0.58 cm3/g).
Библиографическая ссылка: Potylitsyna A.R. , Bauman Y.I. , Ayupov A.B. , Plyusnin P.E. , Shubin Y.V. , Stoyanovskii V.O. , Vedyagin A.A. , Mel'gunov M.S. , Korenev S.V. , Mishakov I.V.
Turbostratic Carbon Nanofibers Produced from C2HCl3 over Self-Dispersing Ni-Catalyst Doped with W and Mo
Diamond and Related Materials. 2024. V.148. 111416 :1-12. DOI: 10.1016/j.diamond.2024.111416 WOS Scopus РИНЦ OpenAlex CAPlus
Даты:
Поступила в редакцию: 25 июн. 2024 г.
Принята к публикации: 11 июл. 2024 г.
Опубликована online: 14 июл. 2024 г.
Опубликована в печати: 1 окт. 2024 г.
Идентификаторы БД:
≡ Web of science: WOS:001272629900001
≡ Scopus: 2-s2.0-85198556740
≡ РИНЦ: 68956842
≡ OpenAlex: W4400615321
≡ Chemical Abstracts: 2024:1573101
Цитирование в БД:
≡ OpenAlex 2 Сбор данных от 22.02.2026
≡ Scopus 1 Сбор данных от 22.02.2026
≡ Web of science 2 Сбор данных от 20.02.2026
≡ РИНЦ 0 Сбор данных от 22.02.2026
Альметрики: