Nonheme Fe Based Enzyme Mimics for Fine Organic Synthesis: Catalytic C‒H and C=C Oxygenations Full article
| Journal |
European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690 |
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| Output data | Year: 2024, Article number : e202400664, Pages count : 8 DOI: 10.1002/ejoc.202400664 | ||||
| Tags | C-H activation · enzyme models · homogeneous catalysis · iron · selective oxygen | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 22-13-00225 |
Abstract:
Since the milestone contribution by Chen and White in 2007, bioinspired non-heme bis-amino-bis-pyridylmethyl Fe complexes have been at the forefront of studies related to designing catalytic approaches for direct oxidative functionalization of aliphatic C-H bonds. This, however, has not developed into large-scale synthetic applications to date. The present concept is aimed at briefly discussing the state-of-the-art of non-heme Fe catalyzed oxidations of organic molecules with H2O2, the current oxidant of choice of bioinspired oxidation catalysis, mostly focusing on C-H oxidations, and analyzing the peculiarities of their reactivity through the prism of potential applications in fine organic synthesis.
Cite:
Talsi E.P.
, Bryliakov K.P.
Nonheme Fe Based Enzyme Mimics for Fine Organic Synthesis: Catalytic C‒H and C=C Oxygenations
European Journal of Organic Chemistry. 2024. e202400664 :1-8. DOI: 10.1002/ejoc.202400664 WOS Scopus РИНЦ AN OpenAlex
Nonheme Fe Based Enzyme Mimics for Fine Organic Synthesis: Catalytic C‒H and C=C Oxygenations
European Journal of Organic Chemistry. 2024. e202400664 :1-8. DOI: 10.1002/ejoc.202400664 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Jun 14, 2024 |
| Accepted: | Jul 8, 2024 |
| Published online: | Jul 8, 2024 |
Identifiers:
| Web of science: | WOS:001295453700001 |
| Scopus: | 2-s2.0-85201717363 |
| Elibrary: | 73521325 |
| Chemical Abstracts: | 2024:1817576 |
| OpenAlex: | W4400418386 |
Citing:
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