Abstract: Since the milestone contribution by Chen and White in 2007, bioinspired non-heme bis-amino-bis-pyridylmethyl Fe complexes have been at the forefront of studies related to designing catalytic approaches for direct oxidative functionalization of aliphatic C-H bonds. This, however, has not developed into large-scale synthetic applications to date. The present concept is aimed at briefly discussing the state-of-the-art of non-heme Fe catalyzed oxidations of organic molecules with H2O2, the current oxidant of choice of bioinspired oxidation catalysis, mostly focusing on C-H oxidations, and analyzing the peculiarities of their reactivity through the prism of potential applications in fine organic synthesis.

Cite: Talsi E.P. , Bryliakov K.P.
Nonheme Fe Based Enzyme Mimics for Fine Organic Synthesis: Catalytic C‒H and C=C Oxygenations
European Journal of Organic Chemistry. 2024. V.27. N40. e202400664 :1-8. DOI: 10.1002/ejoc.202400664 WOS Scopus РИНЦ AN OpenAlex

Dates:

Submitted:	Jun 14, 2024
Accepted:	Jul 8, 2024
Published online:	Jul 8, 2024
Published print:	Oct 21, 2024

Identifiers:

Web of science:	WOS:001295453700001
Scopus:	2-s2.0-85201717363
Elibrary:	73521325
Chemical Abstracts:	2024:1817576
OpenAlex:	W4400418386

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