Conversion of Ethanol into Hydrocarbon Components of Fuels in the Presence of Pd—Zn_Containing Catalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

Conversion of Ethanol into Hydrocarbon Components of Fuels in the Presence of Pd—Zn_Containing Catalyst Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2014, Volume: 63, Number: 1, Pages: 88-93 Pages count : 6 DOI: 10.1007/s11172-014-0399-8

Tags

Biofuel, Ethanol, EXAFS spectroscopy, Heterogeneous catalysis, Structural studies, Transmission electron microscopy, X-ray diffraction analysis, XANES spectroscopy

Authors

Chistyakov A.V. ¹ , Gubanov M.A. ¹ , Murzin V.Yu. ^1,2 , Zharova P.A. ¹ , Tsodikov M.V. ¹ , Kriventsov V.V. ³ , Gekhman A.E. ⁴ , Moiseev I.I. ⁴

Affiliations

1	A. V. Topchiev Institute of Peterochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 119991 Moscow, Russian Federation
2	National Research Center "Kurchatovskii Institut," 1 pl. Akad. Kurchatova, 123182 Moscow, Russian Federation
3	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent'eva, 630090 Novosibirsk, Russian Federation
4	N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991 Moscow, Russian Federation

Funding (6)

1	Russian Foundation for Basic Research	12-03-00489
2	Russian Foundation for Basic Research	12-03-33062 (01201351602)
3	Russian Foundation for Basic Research	13-03-12034 (01201367680)
4	The Ministry of Education and Science of the Russian Federation	14.516.11.0070
5	Council for Grants of the President of the Russian Federation	МК-2151.2012.3
6	Council for Grants of the President of the Russian Federation	НШ-5232.2012.03

The features of ethanol conversion into hydrocarbons C4-C12 in the presence of the novel catalyst Pd-Zn/γ-alumina and pilot zeolite system Pd-Zn/MFI/γ-alumina were studied (MFI is high-siliceous zeolite with ZSM-5 type structure). The structure of active sites changes noticeably in the course of preliminary activation and catalytic reaction. High selectivity and stability of the zeolite-containing Pd-Zn catalyst in alcohol conversion into hydrocarbon components of fuels is related to the stable composition of the alloy that forms clusters PdZn. At the same time, the alumina-based catalyst loses stability due to zinc diffusion from the alloy into γ-Al2O3 to form the spinel structure

Chistyakov A.V. , Gubanov M.A. , Murzin V.Y. , Zharova P.A. , Tsodikov M.V. , Kriventsov V.V. , Gekhman A.E. , Moiseev I.I.
Conversion of Ethanol into Hydrocarbon Components of Fuels in the Presence of Pd—Zn_Containing Catalyst
Russian Chemical Bulletin. 2014. V.63. N1. P.88-93. DOI: 10.1007/s11172-014-0399-8 WOS Scopus РИНЦ ANCAN OpenAlex

Чистяков А.В. , Губанов М.А. , Мурзин В.Ю. , Жарова П.А. , Цодиков М.В. , Кривенцов В.В. , Гехман А.Е. , Моисеев И.И.
Превращение этанола в углеводородные компоненты топлив в присутствии Pd-Zn-содержащих катализаторов
Известия Академии наук. Серия химическая. 2014. №1. С.88-93. РИНЦ

Submitted:	Oct 3, 2013
Published print:	Jan 1, 2014
Published online:	Sep 2, 2014

Web of science:	WOS:000341630700012
Scopus:	2-s2.0-84906852531
Elibrary:	23987080
Chemical Abstracts:	2014:1465652
Chemical Abstracts (print):	161:434636
OpenAlex:	W2054585636

DB	Citing
Web of science	9
Scopus	10
Elibrary	13
OpenAlex	10