Influence of Cu:Fe Ratio in Synthesis of Higher Alcohols from Syngas over CuFeCoK/Attapulgite Catalysts | Sciact - CRIS-система Института катализа

Influence of Cu:Fe Ratio in Synthesis of Higher Alcohols from Syngas over CuFeCoK/Attapulgite Catalysts Научная публикация

Журнал

Applied Catalysis O: Open
ISSN: 2950-6484

Вых. Данные

Год: 2024, Том: 193, Номер статьи : 206972, Страниц : 18 DOI: 10.1016/j.apcato.2024.206972

Ключевые слова

Syngas; Higher alcohols; Copper; Iron; Attapulgite

Авторы

Aho Atte ¹ , Lind Noora ¹ , Virtanen Pasi ¹ , Mäki-Arvela Päivi ¹ , Eränen Kari ¹ , Granroth Sari ² , Korpelin Ville ³ , Honkala Karoliina ³ , Russo Vincenzo ⁴ , Simakova Irina ¹ , Murzin Dmitry Yu. ¹

Организации

1	Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Åbo, Finland
2	Department of Physics and Astronomy, University of Turku, Turku, Finland
3	Department of Chemistry, University of Jyväskylä, Jyväskylä, Finland
4	Università di Napoli Federico II, Napoli, Italy

Synthesis of higher alcohols from syngas (H2:CO ratio 2 and 1) was performed at 225–300 °C and 30 bar over copper, iron and cobalt containing catalysts supported on attapulgite and promoted with potassium. The Cu:Fe ratio was varied to study its influence on the syngas conversion and product distribution. It was found that while the copper rich catalyst 17Cu3FeCoK/attapulgite resulted in higher selectivity to the undesired alkanes with methane as the major one, the iron rich 3Cu17FeCoK/attapulgite was more selective towards alkenes. Selectivity to CO2 was independent on the Cu:Fe ratio tested in this work. With the higher H2:CO ratio (i.e. 2) selectivity to the liquid products increased with the increasing iron content. Moreover, a higher iron content in the catalyst improved formation of higher alcohols while the α-value reflecting the chain growth probability was more or less independent on the catalyst type.

Aho A. , Lind N. , Virtanen P. , Mäki-Arvela P. , Eränen K. , Granroth S. , Korpelin V. , Honkala K. , Russo V. , Simakova I. , Murzin D.Y.
Influence of Cu:Fe Ratio in Synthesis of Higher Alcohols from Syngas over CuFeCoK/Attapulgite Catalysts
Applied Catalysis O: Open. 2024. V.193. 206972 :1-18. DOI: 10.1016/j.apcato.2024.206972 OpenAlex

Поступила в редакцию:	14 мая 2024 г.
Принята к публикации:	28 июн. 2024 г.
Опубликована online:	2 июл. 2024 г.
Опубликована в печати:	1 авг. 2024 г.

OpenAlex:

W4400235149

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