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Dynamics of Water Adsorption on SAPO-34: Comparison of Three Adsorbent Bed Configurations of Adsorption Chillers Full article

Journal Applied Thermal Engineering
ISSN: 1359-4311 , E-ISSN: 1873-5606
Output data Year: 2024, Volume: 256, Article number : 124058, Pages count : 10 DOI: 10.1016/j.applthermaleng.2024.124058
Tags Water adsorption dynamics; Adsorption chiller; SAPO-34; Adsorbent coating; Loose beads; Binder
Authors Strelova S.V. 1 , Solovyeva M.V. 1 , Gordeeva L.G. 1 , Aristov Yu.I. 1
Affiliations
1 Boreskov Institute of Catalysis, Ak. Lavrentiev Av. 5, Novosibirsk, 630055, Russia

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation FWUR-2024-0036

Abstract: Intensification of the adsorption dynamics is a strategic way to make adsorption chillers and heat pumps more competitive with conventional vapour compression systems. This can be achieved by consolidating the adsorbent bed with a heat exchanger to enhance heat transfer. This work investigates the dynamics of water adsorption on a commercial adsorbent SAPO-34 for three bed configurations, namely, a reference bed consisting of a monolayer of loose beads located on an aluminium plate, and two consolidated beds – a monolayer of beads glued to the plate, and a homogeneous coating of the plate prepared with binder. The morphology and texture of the prepared beds were studied by optical and scanning electron microscope techniques as well as by low temperature nitrogen adsorption. Six binders involved, both organic (hydroxyethyl cellulose, polyvinylpyrrolidone, polyaniline) and inorganic (heat-conductive compound CPTD, bentonite clay, colloidal silica sol), produced varying effects. It was found that the most preferred configuration involves SAPO beads glued to the plate with bentonite for which the heat transfer was enhanced by a factor of 1.2–1.7 while maintaining sufficient mass transfer. The effective heat transfer coefficient was measured for the most promising binders and selected configurations, and varied between 120 and 248 W/(m2 K). The heat transfer acceleration permitted the specific cooling power (at a conversion of 0.8) to increase from 2.7 kW/kg for loose beads of 0.8–0.9 mm size to 3.5 kW/kg for the same beads bound with bentonite. Thus, gluing pre-made commercial adsorbent beads with heat-exchanger with suitable binders presents a simple and promising method to enhance the adsorption dynamics, resulting in a more compact design of adsorption chillers.
Cite: Strelova S.V. , Solovyeva M.V. , Gordeeva L.G. , Aristov Y.I.
Dynamics of Water Adsorption on SAPO-34: Comparison of Three Adsorbent Bed Configurations of Adsorption Chillers
Applied Thermal Engineering. 2024. V.256. 124058 :1-10. DOI: 10.1016/j.applthermaleng.2024.124058 WOS Scopus AN OpenAlex
Dates:
Submitted: Mar 20, 2024
Accepted: Jul 26, 2024
Published online: Jul 27, 2024
Published print: Nov 1, 2024
Identifiers:
Web of science: WOS:001290179700001
Scopus: 2-s2.0-85200518794
Chemical Abstracts: 2024:1711654
OpenAlex: W4401043737
Citing:
DB Citing
Scopus 5
OpenAlex 3
Web of science 3
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