Organic Synthesis in Flow Mode by Selective Liquid-Phase Hydrogenation over Heterogeneous non-Noble Metal Catalysts Review
| Journal |
Organic and Biomolecular Chemistry
ISSN: 1477-0520 , E-ISSN: 1477-0539 |
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| Output data | Year: 2024, Volume: 22, Number: 29, Pages: 7936-7950 Pages count : 15 DOI: 10.1039/d4ob00873a | ||
| Tags | supported copper-catalysts; reductive amination; secondary-amines; levulinic acid; cobalt oxide; biomass; nitroarenes; conversion; chemistry; aldehydes | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | FWUR-2024-0035 |
Abstract:
Flow hydrogenation performed over heterogeneous catalysts makes organic synthesis more economical, safe and environmentally friendly. Over the past two decades, a significant amount of research with a major focus on noble metal catalysts has been carried out in this area. However, catalysts based on non-noble metals (Ni, Cu, Co, etc.) are more promising for practical use due to their low cost and high availability. This review article discusses the use of supported and bulk non-noble metal catalysts for the liquid-phase hydrogenation of bi- and polyfunctional organic compounds in flow mode. The main attention is paid to the selective reduction of one functional group (NO2, C=C, C≡N, C=O, and C=N) in the presence of other substituents. In addition, cascade synthetic protocols involving hydrogenation are presented.
Cite:
Nuzhdin A.L.
, Bukhtiyarova M.V.
, Bukhtiyarova G.A.
Organic Synthesis in Flow Mode by Selective Liquid-Phase Hydrogenation over Heterogeneous non-Noble Metal Catalysts
Organic and Biomolecular Chemistry. 2024. V.22. N29. P.7936-7950. DOI: 10.1039/d4ob00873a WOS Scopus РИНЦ ANCAN PMID OpenAlex
Organic Synthesis in Flow Mode by Selective Liquid-Phase Hydrogenation over Heterogeneous non-Noble Metal Catalysts
Organic and Biomolecular Chemistry. 2024. V.22. N29. P.7936-7950. DOI: 10.1039/d4ob00873a WOS Scopus РИНЦ ANCAN PMID OpenAlex
Dates:
| Submitted: | May 24, 2024 |
| Accepted: | Sep 2, 2024 |
| Published online: | Sep 3, 2024 |
| Published print: | Oct 21, 2024 |
Identifiers:
| Web of science: | WOS:001308828000001 |
| Scopus: | 2-s2.0-85204155207 |
| Elibrary: | 74641461 |
| Chemical Abstracts: | 2024:1966275 |
| Chemical Abstracts (print): | 188:183194 |
| PMID: | 39254682 |
| OpenAlex: | W4402173172 |