Sciact
  • EN
  • RU

Vacuum Gasoil Hydrocracking over Three-Layered Packages Consisting of Supported Sulfide NiMo and NiW Catalysts Full article

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2014, Volume: 6, Number: 4, Pages: 320-328 Pages count : 9 DOI: 10.1134/S2070050414040060
Tags Catalysts package, Hydrocracking, Vacuum gasoil
Authors Dik P.P. 1 , Pereyma V.Yu. 1 , Klimov O.V. 1 , Koryakina G.I. 1 , Budukva S.V. 1 , Leonova K.A. 1 , Gerasimov E.Yu. 1,2 , Danilova I.G. 1 , Noskov A.S. 1
Affiliations
1 Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Novosibirsk National Research University, Novosibirsk, 630090 Russia

Funding (1)

1 Federal Agency for Scientific Organizations V.46.2.7.

Abstract: A method for vacuum gas oil hydrocracking using a three-layered package of catalysts is proposed, in which the top layer is NiMo/Al2O3, the middle is NiM/AAS-Al2O3 and the bottom is NiM/Y-Al2O3, where M is molybdenum or tungsten, AAS-Al2O3 is a support with 70% amorphous aluminosilicate (AAS) and 30% aluminum oxide, and Y is an Al2O3 support with 30% zeolite Y and 70% alumina. The acidic properties of the catalysts are studied via the IR spectroscopy of adsorbed CO. The morphology of sulfide particles on a catalyst’s surface is studied by means of transmission electron microscopy. Textural characteristics of the supports and catalysts are studied via nitrogen porosimetry. Packages containing NiMo and NiW catalysts in different combinations are tested in the hydrocracking of vacuum gas oil. It is shown that replacing NiMo/AAS-Al2O3 with NiW/AAS-Al2O3 in a catalyst package containing only NiMo considerably raises the yield of the diesel fraction
Cite: Dik P.P. , Pereyma V.Y. , Klimov O.V. , Koryakina G.I. , Budukva S.V. , Leonova K.A. , Gerasimov E.Y. , Danilova I.G. , Noskov A.S.
Vacuum Gasoil Hydrocracking over Three-Layered Packages Consisting of Supported Sulfide NiMo and NiW Catalysts
Catalysis in Industry. 2014. V.6. N4. P.320-328. DOI: 10.1134/S2070050414040060 WOS Scopus РИНЦ OpenAlex
Original: Дик П.П. , Перейма В.Ю. , Климов О.В. , Корякина Г.И. , Будуква С.В. , Леонова К.А. , Герасимов Е.Ю. , Данилова И.Г. , Носков А.С.
Гидрокрекинг вакуумного газойля на трехслойных пакетах, состоящих их нанесенных сульфидных Ni-Mo и Ni-W катализаторов
Катализ в промышленности. 2014. №5. С.65-73. РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jun 10, 2014
Published print: Oct 1, 2014
Published online: Dec 24, 2014
Identifiers:
Web of science: WOS:000433673400011
Scopus: 2-s2.0-84920133586
Elibrary: 24027408
OpenAlex: W1968935836
Citing:
DB Citing
Scopus 1
Elibrary 1
OpenAlex 1
Web of science 1
Altmetrics: