Effect of Microwave Irradiation on the Synthesis of Zeolite with Ferrierite Structure: Study of Acid and Catalytic Properties | Sciact - CRIS-system of Boreskov Institute of Catalysis

Effect of Microwave Irradiation on the Synthesis of Zeolite with Ferrierite Structure: Study of Acid and Catalytic Properties Full article

Journal

Colloids and Surfaces A: Physicochemical and Engineering Aspects
ISSN: 0927-7757

Output data

Year: 2024, Volume: 703, Number: 2, Article number : 135321, Pages count : 10 DOI: 10.1016/j.colsurfa.2024.135321

Tags

Ferrierite, Microwave synthesis, 1,5-Benzodiazepine, 1,2-Phenylenediamine, Acetone

Authors

Makova Anna S. ^1,2 , Timofeeva Maria N. ^1,3 , Tkachenko Olga P. ¹ , Panchenko Valentina N. ³ , Leonov Alexander V. ⁴ , Kapustin Gennady I. ¹ , Davshan Nikolay A. ¹ , Kalmykov Konstantin B. ⁴ , Kustov Alexander L. ^2,4 , Ter-Akopyan Marina N. ² , Kustov Leonid M. ^1,2,4

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Pr. Leninsky, 47, Moscow 11991, Russian Federation
2	National University of Science and Technology ‘MISIS’, Pr. Leninsky, 4, Moscow 119049, Russian Federation
3	G. K. Boreskov Institute of Catalysis SB RAS, Pr. Akad. Lavrentieva, 5, Novosibirsk 630090, Russian Federation
4	Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow 119234, Russian Federation

Funding (2)

1	Russian Science Foundation	23-73-30007 (123042000027-5)(FFZZ-2022-0005)
2	Ministry of Science and Higher Education of the Russian Federation	FWUR-2024-0035

Ferrierite zeolite (FER) was synthesized under microwave conditions while varying the microwave exposure time from 6 to 12 h. For comparison, commercial FER and a FER zeolite synthesized by the conventional hydrothermal synthesis (72 h) were studied. The structure, texture, and acidic properties of the samples were investigated by XRD, low-temperature N2 adsorption, ICP-AES, SEM, and DRIFT spectroscopy using adsorption of CO, CD3CN and pyridine as probe molecules. The catalytic characteristics of the obtained zeolites were studied in the cyclocondensation reaction of 1,2-phenylenediamine and acetone to produce 1,5-benzodiazepine. The activity of the zeolites in this reaction was found to increase with increasing microwave exposure time. The FER-MW sample synthesized in 12 h showed the best results.

Makova A.S. , Timofeeva M.N. , Tkachenko O.P. , Panchenko V.N. , Leonov A.V. , Kapustin G.I. , Davshan N.A. , Kalmykov K.B. , Kustov A.L. , Ter-Akopyan M.N. , Kustov L.M.
Effect of Microwave Irradiation on the Synthesis of Zeolite with Ferrierite Structure: Study of Acid and Catalytic Properties
Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2024. V.703. N2. 135321 :1-10. DOI: 10.1016/j.colsurfa.2024.135321 WOS Scopus ANCAN OpenAlex

Submitted:	Jul 19, 2024
Accepted:	Sep 9, 2024
Published online:	Sep 17, 2024
Published print:	Nov 1, 2024

Web of science:	WOS:001321602700001
Scopus:	2-s2.0-85204390181
Chemical Abstracts:	2024:2041395
Chemical Abstracts (print):	188:323307
OpenAlex:	W4402565337

DB	Citing
Scopus	1
Web of science	1
OpenAlex	1