X-Ray Photoelectron Spectroscopy Study of the Charge and Spin States of Atoms in the Tetranuclear Copper(II) Complex with the Nitroxyl Radical (L) of the Composition Cu4(OH)2(OAc)4(DMF)2(L)2 | Sciact - CRIS-system of Boreskov Institute of Catalysis

X-Ray Photoelectron Spectroscopy Study of the Charge and Spin States of Atoms in the Tetranuclear Copper(II) Complex with the Nitroxyl Radical (L) of the Composition Cu4(OH)2(OAc)4(DMF)2(L)2 Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2014, Volume: 63, Number: 4, Pages: 826-832 Pages count : 7 DOI: 10.1007/s11172-014-0516-8

Tags

Copper(II) complexes with the nitroxyl radical, DFT, X-ray photoelectron spectroscopy

Authors

Mazalov L.N. ^1,2 , Kryuchkova N.A. ^1,2 , Fedorenko A.D. ¹ , Kalinkin A.V. ³ , Tretyakov E.V. ⁴

Affiliations

1	A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090 Novosibirsk, Russian Federation
2	Novosibirsk State University, 2 ul. Pirogova, 630090 Novosibirsk, Russian Federation
3	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent´eva, 630090 Novosibirsk, Russian Federation
4	International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090 Novosibirsk, Russian Federation

Funding (5)

1	Russian Foundation for Basic Research	12-03-00067
2	Russian Foundation for Basic Research	12-03-00558
3	Russian Foundation for Basic Research	13-03-12401
4	Siberian Branch of the Russian Academy of Sciences
5	Президиум РАН

The charge and spin states of atoms in the copper(II) complex with the nitroxyl radical (L) of the composition Cu4(OH)2(OAc)4(DMF)2(L)2 were studied by X-ray photoelectron spectroscopy and compared with the data of quantum chemical calculations. The spectra of copper represent a superposition of the |C−13d9〉 and |C−13d10 L〉 electronic states (C−1 = 2p5 or 3s1). All copper ions in the complex have the close-lying charge and spin states.

Mazalov L.N. , Kryuchkova N.A. , Fedorenko A.D. , Kalinkin A.V. , Tretyakov E.V.
X-Ray Photoelectron Spectroscopy Study of the Charge and Spin States of Atoms in the Tetranuclear Copper(II) Complex with the Nitroxyl Radical (L) of the Composition Cu4(OH)2(OAc)4(DMF)2(L)2
Russian Chemical Bulletin. 2014. V.63. N4. P.826-832. DOI: 10.1007/s11172-014-0516-8 WOS Scopus РИНЦ ANCAN OpenAlex

Мазалов Л.Н. , Крючкова Н.А. , Федоренко А.Д. , Калинкин А.В. , Третьяков Е.В.
Рентгеноэлектронное изучение зарядового и спинового состояния атомов в тетраядерном комплексе меди(II) с нитроксильным радикалом (L) состава Cu4(OH)2(OАc)4(DMF)2(L)2
Известия Академии наук. Серия химическая. 2014. №4. С.826-832. РИНЦ

Submitted:	Dec 26, 2013
Published print:	Apr 1, 2014
Published online:	Jan 27, 2015

Web of science:	WOS:000348593900005
Scopus:	2-s2.0-84921792699
Elibrary:	24030522
Chemical Abstracts:	2015:172892
Chemical Abstracts (print):	162:307726
OpenAlex:	W2030662471

DB	Citing
Web of science	2
Scopus	2
Elibrary	2
OpenAlex	2