Catalytic Performance of a Single Atom Pd1Ag10/Al2O3 Catalyst for the Selective Hydrogenation of Acetylene: The Role of CO-Induced Segregation Full article
Journal |
Applied Surface Science
ISSN: 0169-4332 |
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Output data | Year: 2025, Volume: 681, Article number : 161516, Pages count : 10 DOI: 10.1016/j.apsusc.2024.161516 | ||||||
Tags | Pd-Ag nanoparticles; Single atom alloy; Adsorption-induced segregation; XPS; DRIFTS-CO; Selective hydrogenation | ||||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Science Foundation | 23-13-00301 |
2 | Ministry of Science and Higher Education of the Russian Federation | FWUR-2024-0042 |
Abstract:
The single-atom Pd catalysts based on silver-rich bimetallic compositions are known for their extremely high ethylene selectivity in the acetylene hydrogenation reaction; however, their activity is noticeably lower than that of traditional monometallic Pd catalysts. The aim of the work was to apply a method of CO-induced segregation to increase the concentration of single atom Pd1 sites on the surface of Pd1Ag10/Al2O3 catalyst without noticeable formation of multiatomic Pdn (n ≥ 2) ensembles. It has been experimentally established by DRIFTS-CO and XPS methods that the effect of 30 vol% CO exposure temperature on the increase of surface Pd1 sites concentration in the range of 50 to 350 °C has a volcano-like dependence with a maximum at ∼ 200–250 °C. The catalytic tests show a considerable enhancement in activity for samples treated in CO at 200–250 °C (the temperature of 100 % acetylene conversion is reduced by ∼ 30 °C), while the C2H4 selectivity was similar for both freshly reduced and CO-treated catalysts. These results demonstrate the use of CO-induced segregation as a promising method for the controlled increase in the concentration of isolated Pd1 sites to improve the activity of silver-rich palladium catalyst without compromising its selectivity.
Cite:
Mashkovsky I.S.
, Bukhtiyarov A.V.
, Markov P.V.
, Bragina G.O.
, Baeva G.N.
, Smirnova N.S.
, Panafidin M.A.
, Chetyrin I.A.
, Gerasimov E.Y.
, Zubavichus Y.V.
, Stakheev A.Y.
Catalytic Performance of a Single Atom Pd1Ag10/Al2O3 Catalyst for the Selective Hydrogenation of Acetylene: The Role of CO-Induced Segregation
Applied Surface Science. 2025. V.681. 161516 :1-10. DOI: 10.1016/j.apsusc.2024.161516 WOS Scopus OpenAlex
Catalytic Performance of a Single Atom Pd1Ag10/Al2O3 Catalyst for the Selective Hydrogenation of Acetylene: The Role of CO-Induced Segregation
Applied Surface Science. 2025. V.681. 161516 :1-10. DOI: 10.1016/j.apsusc.2024.161516 WOS Scopus OpenAlex
Dates:
Submitted: | Aug 1, 2024 |
Accepted: | Oct 11, 2024 |
Published online: | Oct 12, 2024 |
Published print: | Feb 1, 2025 |
Identifiers:
Web of science: | WOS:001340395000001 |
Scopus: | 2-s2.0-85206460174 |
OpenAlex: | W4403348623 |
Citing:
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