Kinetic Models for the Methanation of COx Gases to Produce Methane: A Critical Analysis | Sciact - CRIS-system of Boreskov Institute of Catalysis

Kinetic Models for the Methanation of COx Gases to Produce Methane: A Critical Analysis Full article

Journal

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Output data

Year: 2024, Volume: 93, Pages: 387-402 Pages count : 16 DOI: 10.1016/j.ijhydene.2024.10.378

Tags

COx methanation reactions; Kinetic models; Natural gas; Energy transition

Authors

Ríos Juan J. ¹ , Ancheyta Jorge ^2,3 , Mantilla Ángeles ¹ , Elyshev Andrey ³ , Zagoruiko Andrey ⁴

Affiliations

1	Instituto Politecnico Nacional, Centro de Investigacion en Ciencia Aplicada y Tecnología Avanzada, Unidad Legaria. Legaria 694, Col. Irrigacion, 11500, Ciudad de Mexico, Mexico
2	E.S.I.Q.I.E., Instituto Politecnico Nacional, UPALM, Zacatenco, Mexico City, 07738, Mexico
3	Tyumen State University, Tyumen, Russia
4	Boreskov Institute of Catalysis, Novosibirsk, Russia

Funding (3)

1	National Council of Science and Technology
2	National Polytechnic Institute	20240484
3	Ministry of Science and Higher Education of the Russian Federation	FEWZ-2024-0015

An exhaustive review of the available literature regarding the kinetic models for the methanation of COx gases to produce natural gas (CH4) is reported. Since the oldest and recent reported kinetic studies about this topic were discussed and analyzed. The characteristics of the experimental studies such as the reaction system, operating conditions, catalyst used, and the experimental procedure, as well as the derived reaction rate equations, reaction rate coefficients and activation energies are highlighted. The results of the various kinetic models are also discussed in order to identify appropriate approaches that can be used as reference to develop new kinetic models. Most of the works reported values of reaction order of 0.2–1 and activation energies of 75–110 kJ/mol in a temperature range of 220–450 °C. Average absolute error (ε) values were calculated to evaluate the accuracy of the predicted data, which resulted to be in the range of 0.15 %–8.08 % showing generally a good agreement.

Ríos J.J. , Ancheyta J. , Mantilla Á. , Elyshev A. , Zagoruiko A.
Kinetic Models for the Methanation of COx Gases to Produce Methane: A Critical Analysis
International Journal of Hydrogen Energy. 2024. V.93. P.387-402. DOI: 10.1016/j.ijhydene.2024.10.378 WOS Scopus AN OpenAlex

Submitted:	Jun 5, 2024
Accepted:	Oct 27, 2024
Published online:	Nov 3, 2024
Published print:	Dec 3, 2024

Web of science:	WOS:001350479300001
Scopus:	2-s2.0-85207768103
Chemical Abstracts:	2024:2407988
OpenAlex:	W4404009121

DB	Citing
Scopus	3
OpenAlex	3
Web of science	3