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Liquid Phase Peroxide Oxidation of Phenol in the Presence of Catalysts Based on Mixed Oxides of Transition Metals and Cellulose Full article

Journal Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296
Output data Year: 2024, Volume: 97, Number: 5, Pages: 486-499 Pages count : 14 DOI: 10.1134/S1070427224050021
Tags wastewater, phenol, liquid-phase peroxide oxidation, ferrites
Authors Perebeinos A.A. 1 , Mishchenko T.I. 2 , Gurovskii V.V. 1 , Medvedeva T.B. 2 , Yatsenko D.A. 2 , Gromov N.V. 1,2
Affiliations
1 Novosibirsk State Technical University, Novosibirsk, 630073 Russia
2 Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (2)

1 Ministry of Science and Higher Education of the Russian Federation FWUR-2024-0036
2 Ministry of Science and Higher Education of the Russian Federation ТП-ИПЭ-1-24

Abstract: The work is devoted to the study of the process of water purification from phenol, which was oxidized in the process of liquid-phase peroxide oxidation in the presence of catalysts of composite materials based on MeFe2O4 (Me = Mn, Co, Mg, Cu) and cellulose. The textural and acidic properties of the catalysts were studied. It was shown that the main phase of the catalysts is MeFe2O4, acidity of aqueous suspensions of catalysts are neutral and slightly alkaline. Among the tested catalysts, the CuFe2O4/CMC (microcrystalline cellulose) sample had the greatest efficiency, in the presence of which the phenol conversion was achieved 100% for 20 min of reaction time. Copper and manganese had the greatest effectiveness as Me in the MeFe2O4/CMC system.
Cite: Perebeinos A.A. , Mishchenko T.I. , Gurovskii V.V. , Medvedeva T.B. , Yatsenko D.A. , Gromov N.V.
Liquid Phase Peroxide Oxidation of Phenol in the Presence of Catalysts Based on Mixed Oxides of Transition Metals and Cellulose
Russian Journal of Applied Chemistry. 2024. V.97. N5. P.486-499. DOI: 10.1134/S1070427224050021 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: May 1, 2024
Submitted: Jul 4, 2024
Accepted: Nov 11, 2024
Identifiers:
Web of science: WOS:001380840400003
Scopus: 2-s2.0-85212503120
Elibrary: 75220653
OpenAlex: W4405511709
Citing: Пока нет цитирований
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