Diffusion in Nanoporous Materials with Special Consideration of the Measurement of Determining Parameters (IUPAC Technical Report) | Sciact - CRIS-system of Boreskov Institute of Catalysis

Diffusion in Nanoporous Materials with Special Consideration of the Measurement of Determining Parameters (IUPAC Technical Report) Full article

Journal

Pure and Applied Chemistry
ISSN: 0033-4545 , E-ISSN: 1365-3075

Output data

Year: 2025, Volume: 97, Number: 1, Pages: 1-89 Pages count : 89 DOI: 10.1515/pac-2023-1126

Tags

Mass transfer; nanostructured materials; physical and biophysical chemistry division

Authors

Kärger Jörg ¹ , Valiullin Rustem ¹ , Brandani Stefano ² , Caro Jürgen ³ , Chmelik Christian ¹ , Chmelka Bradley F. ⁴ , Coppens Marc-Olivier ⁵ , Farooq Shamsuzzaman ⁶ , Freude Dieter ¹ , Jobic Hervé ⁷ , Kruteva Margarita ⁸ , Mangano Enzo ² , Pini Ronny ⁹ , Price William S. ¹⁰ , Rajendran Arvind ¹¹ , Ravikovitch Peter I. ¹² , Sastre German ¹³ , Snurr Randall Q. ¹⁴ , Stepanov Alexander G. ¹⁵ , Vasenkov Sergey ¹⁶ , Wang Yu ¹² , Weckhuysen Bert M. ¹⁷

Affiliations

1	Faculty of Physics and Earth System Sciences, Leipzig University, Leipzig , Germany
2	School of Engineering, University of Edinburgh, Edinburgh, UK
3	Institute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Hannover, Germany
4	University of California, Santa Barbara, CA 93106-5080, USA
5	University College London, Gower Street, London, WC1E 6BT , UK
6	Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore, Singapore
7	CNRS, Institut de Recherches sur la Catalyse, Villeurbanne, France
8	Jülich Center for Neutron Science, Jülich, Germany
9	Department of Chemical Engineering, Imperial College London, London , UK
10	School of Science and Health, Western Sydney University, Penrith , Australia
11	Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Canada
12	ExxonMobil Technology and Engineering, Annandale, USA
13	Instituto de Tecnologia Quimica, Univesidad Politecnica de Valencia, Valencia, Spain
14	Department of Chemical and Biological Engineering, Northwestern University, Evanston, USA
15	Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia
16	Department of Chemical Engineering, University of Florida, Gainesville, USA
17	Debye Institute for Nanomaterials Science and Institute for Sustainable and Circular Chemistry, Utrecht University, Utrecht, The Netherlands

Funding (1)

International Union of Pure and Applied Chemistry

2015-002-2-100

The random motion (the diffusion) of guest molecules in nanoporous host materials is key to their manifold technological applications and, simultaneously, a ubiquitous phenomenon in nature quite in general. Based on a specification of the different conditions under which molecular diffusion in nanoporous materials may occur and of the thus resulting relevant parameters, a survey of the various ways of the measurement of the determining parameters is given. Starting with a condensed introduction to the respective measuring principles, the survey notably includes a summary of the various parameters accessible by each individual technique, jointly with an overview of their strengths and weaknesses as well as of the respective ranges of observation. The presentation is complemented by basic relations of diffusion theory and molecular modeling in nanoporous materials, illustrating their significance for enhancing the informative value of each measuring technique and the added value attainable by their combination. By providing guidelines for the measurement and reporting of diffusion properties of chemical compounds in nanopores, the document aims to contribute to the clarification and standardization of the presentation, nomenclature, and methodology associated with the documentation of diffusion phenomena in nanoporous materials serving for catalytic, mass separation, and other relevant purposes.

Kärger J. , Valiullin R. , Brandani S. , Caro J. , Chmelik C. , Chmelka B.F. , Coppens M-O. , Farooq S. , Freude D. , Jobic H. , Kruteva M. , Mangano E. , Pini R. , Price W.S. , Rajendran A. , Ravikovitch P.I. , Sastre G. , Snurr R.Q. , Stepanov A.G. , Vasenkov S. , Wang Y. , Weckhuysen B.M.
Diffusion in Nanoporous Materials with Special Consideration of the Measurement of Determining Parameters (IUPAC Technical Report)
Pure and Applied Chemistry. 2025. V.97. N1. P.1-89. DOI: 10.1515/pac-2023-1126 WOS Scopus РИНЦ OpenAlex

Submitted:	Nov 16, 2023
Accepted:	Jul 31, 2024
Published online:	Nov 20, 2024

Web of science:	WOS:001357817700001
Scopus:	2-s2.0-85210730997
Elibrary:	79265220
OpenAlex:	W4404501673

DB	Citing
Web of science	1
OpenAlex	1
Scopus	1