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Catalytic Reductive Hydrodefluorination of 1,1-Difluoronaphthalen-2(1H)-one Full article

Journal Chemistry for Sustainable Development
ISSN: 1817-1818
Output data Year: 2024, Volume: 32, Number: 4, Pages: 475-477 Pages count : 3 DOI: 10.15372/CSD2024580
Tags heterogeneous catalysis, palladium catalysis, hydrogenation, fluorinated aromatic compounds, reaction mechanism
Authors Dyan O.T. 1 , Kulagina M.A. 2 , Zaikin P.A. 1
Affiliations
1 Vorozhtsov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
2 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia

Funding (1)

1 Russian Foundation for Basic Research 19-33-60101 (АААА-А19-119110590007-0)

Abstract: An optimised method of 1,1-difluoronaphthalen-2(1H)-one hydrodefluorination leading to the formation of fluoronaphthol under mild conditions is proposed. The palladium-catalysed process is shown to involve carbonyl reduction followed by subsequent hydrogen fluoride (HF) elimination. The structure of the intermediate product and the effect of catalyst support material on hydrodefluorination selectivity have been determined.
Cite: Dyan O.T. , Kulagina M.A. , Zaikin P.A.
Catalytic Reductive Hydrodefluorination of 1,1-Difluoronaphthalen-2(1H)-one
Chemistry for Sustainable Development. 2024. V.32. N4. P.475-477. DOI: 10.15372/CSD2024580 WOS РИНЦ OpenAlex
Original: Дян О.Т. , Кулагина М.А. , Заикин П.А.
Каталитическое восстановительное гидродефторирование 1,1-дифторнафталин-2(1Н)-она
Химия в интересах устойчивого развития. 2024. Т.32. №4. С.491-494. DOI: 10.15372/KhUR2024580 РИНЦ ANCAN OpenAlex
Dates:
Submitted: May 31, 2024
Accepted: Jul 12, 2024
Identifiers:
Web of science: WOS:001358120200001
Elibrary: 74528463
OpenAlex: W4404725993
Citing: Пока нет цитирований
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