Thermolysis of Copper(II) Salts of Maleic Acid. Synthesis of Metal-Polymer Composites | Sciact - CRIS-system of Boreskov Institute of Catalysis

Thermolysis of Copper(II) Salts of Maleic Acid. Synthesis of Metal-Polymer Composites Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2013, Volume: 39, Number: 5, Pages: 415-420 Pages count : 6 DOI: 10.1134/S1070328413050102

Tags

Fumarate; Maleic Acid; Thermolysis; Maleic Anhydride; Maleate Decomposition

Authors

Yudanova L.I. ¹ , Logvinenko V.A. ¹ , Yudanov N.F. ¹ , Rudina N.A. ² , Ishchenko A.V. ² , Semyannikov P.P. ¹ , Sheludyakova L.A. ¹ , Alferova N.I. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

The thermal decomposition of neutral ([Cu(H2O)(C4H2O4)]) and acidic ([Cu(H2O)4](C4H3O4)2) maleates can conventionally be divided into four stages: (1) dehydration, (2) polymerization, (3) isomerization of the maleate ion to the trans form with the simultaneous reduction Cu(II) → Cu(I), and (4) decarboxylation of copper(I) fumarate. The third and fourth stages of the decomposition of these salts coincide. The residue after the thermolysis of copper(II) maleates in a He flow is a composite consisting of aggregates from 50 nm to several microns in size. Spherical conglomerates (50–200 nm) containing many spherical Cu particles (5–10 nm) are incorporated into the organic polymer matrix of these aggregates.

Yudanova L.I. , Logvinenko V.A. , Yudanov N.F. , Rudina N.A. , Ishchenko A.V. , Semyannikov P.P. , Sheludyakova L.A. , Alferova N.I.
Thermolysis of Copper(II) Salts of Maleic Acid. Synthesis of Metal-Polymer Composites
Russian Journal of Coordination Chemistry. 2013. V.39. N5. P.415-420. DOI: 10.1134/S1070328413050102 WOS Scopus РИНЦ ANCAN OpenAlex

Юданова Л.И. , Логвиненко В.А. , Юданов Н.Ф. , Рудина Н.А. , Ищенко А.В. , Семянников П.П. , Шелудякова Л.А. , Алферова Н.И.
Термолиз солей малеиновой кислоты Cu(II). Синтез композитов металл-полимер
Координационная химия. 2013. Т.39. №5. С.309-314. DOI: 10.7868/S0132344X13050101 РИНЦ OpenAlex

Submitted:	Aug 31, 2012
Published print:	May 1, 2013
Published online:	May 9, 2013

Web of science:	WOS:000318573600009
Scopus:	2-s2.0-84877727098
Elibrary:	20428118
Chemical Abstracts:	2013:708342
Chemical Abstracts (print):	159:380652
OpenAlex:	W2048850884

DB	Citing
Web of science	10
Scopus	11
Elibrary	9
OpenAlex	13