Abstract: Polyfunctional nickel-containing catalysts based on B2O3–Al2O3 and MoO3–Al2O3 oxide supports have been synthesized by sequential impregnation and studied in the conversion of ethylene into C5+ alkenes or propylene. The physicochemical properties of the prepared catalysts has been studied using X-ray diffraction analysis, IR spectroscopy, IR spectroscopy of adsorbed CO, UV-Visible diffuse reflectance spectroscopy (UV-Vis DRS), temperature-programmed reduction of hydrogen (H2-TPR), and temperature-programmed desorption of ammonia (TPD-NH3). The most active catalysts of ethylene oligomerization are NiO/B2O3–Al2O3, where Ni2+ cations chemically bounded to the acidic support are formed. NiO/MoO3–Al2O3 activity in conversion of ethylene to propylene is provided by the presence on the surface of ethylene dimerization active sites, i.e., Ni2+ cations bounded with the support acidic sites, and active sites of metathesis based on monomolybdate species.

Cite: Karpova T.R. , Lavrenov A.V. , Moiseenko M.A. , Buluchevskii E.A. , Gulyaeva T.I. , Arbuzov A.B.
Nickel-Containing Catalysts of Ethylene Conversion for Synthesizing Motor Fuel Components and Light Alkenes
Catalysis in Industry. 2024. V.16. N4. P.405–412. DOI: 10.1134/S2070050424700247 WOS Scopus OpenAlex publication_identifier_short.sciact_ihcp_identifier_type

Original: Карпова Т.Р. , Лавренов А.В. , Моисеенко М.А. , Булучевский Е.А. , Гуляева Т.И. , Арбузов А.Б.
Никельсодержащие катализаторы превращения этилена для получения компонентов моторных топлив и легких алкенов
Катализ в промышленности. 2024. Т.24. №2. С.26-33. DOI: 10.18412/1816-0387-2024-2-26-33 РИНЦ AN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type

Dates:

Submitted:	Sep 21, 2023
Accepted:	Oct 25, 2023
Published print:	Dec 1, 2024
Published online:	Jan 27, 2025

Identifiers:

Web of science:	WOS:001408605200012
Scopus:	2-s2.0-85217646235
OpenAlex:	W4406870314
publication_identifier.sciact_ihcp_identifier_type:	4433

Citing: Пока нет цитирований

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