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Mathematical Modeling of Autothermal Light Paraffins Hydrogenolysis Processes Научная публикация

Журнал Energy
ISSN: 0360-5442 , E-ISSN: 1873-6785
Вых. Данные Год: 2025, Том: 319, Номер статьи : 134996, Страниц : 11 DOI: 10.1016/j.energy.2025.134996
Ключевые слова Propane hydrogenolysis; Glass-fiber catalyst; Mathematical modeling; Multi-pass reactor; Reverse-flow process
Авторы Zazhigalov Sergey 1,2 , Sibaa Mokhamd 1 , Sozonov Maxim 1 , Elyshev Andrey 1 , Zagoruiko Andrey 2
Организации
1 University of Tyumen, Tyumen, 625003, Russia
2 Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

Информация о финансировании (2)

1 Российский научный фонд 22-73-10015
2 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) FWUR-2024-0037

Реферат: The work is dedicated to modeling of autothermal reactors based on the novel Ni-containing glass-fiber catalysts (GFCs) for hydrogenolysis of gas condensate components to light transportable gaseous products, first of all, methane. Process evaluation was made using the computational fluid dynamics (CFD) approach based on developed kinetic model for propane hydrogenation. Modelling of the fixed bed reactors with Ni/GFC bed has showed that a multi-pass design with internal walls that form several passes in the reactor allows to achieve complete conversion of propane at inlet temperature of ∼300 °C, while it is not observed at all in the conventional one-pass reactor even at 400 °C. Simulation of the reverse-flow process demonstrated that it may provide the full autothermicity of the light paraffin hydrogenolysis, meaning that the inlet gas may be fed to the reverse-flow reactor without any preheating, e.g. with ambient temperature, with full conversion of propane under technologically acceptable duration of cycles between flow reversals (up to ∼860 s). Ni/GFC in the proposed reactors design look promising from practical point of view, potentially allowing to improve process conversion and energy efficiency, to decrease operational and capital costs and to minimize the size of the hydrogenolysis units.
Библиографическая ссылка: Zazhigalov S. , Sibaa M. , Sozonov M. , Elyshev A. , Zagoruiko A.
Mathematical Modeling of Autothermal Light Paraffins Hydrogenolysis Processes
Energy. 2025. V.319. 134996 :1-11. DOI: 10.1016/j.energy.2025.134996 WOS Scopus OpenAlex
Даты:
Поступила в редакцию: 2 дек. 2024 г.
Принята к публикации: 10 февр. 2025 г.
Опубликована online: 13 февр. 2025 г.
Опубликована в печати: 15 мар. 2025 г.
Идентификаторы БД:
Web of science: WOS:001429068900001
Scopus: 2-s2.0-85217817582
OpenAlex: W4407425591
Цитирование в БД: Пока нет цитирований
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