Catalysts for Ethanol Dry Reforming Based on High-Entropy Perovskites | Sciact - CRIS-система Института катализа

Catalysts for Ethanol Dry Reforming Based on High-Entropy Perovskites Научная публикация

Журнал

Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694

Вых. Данные

Год: 2025, Том: 445, Номер статьи : 116028, Страниц : 31 DOI: 10.1016/j.jcat.2025.116028

Ключевые слова

Bioethanol, carbon dioxide, dry reforming, high-entropy oxides, oxygen diffusion, isotope exchange

Авторы

Eremeev Nikita F. ^1,2 , Hanna Semon A. ¹ , Sadovskaya Ekaterina M. ² , Leonova Aleksandra A. ² , Bulavchenko Olga A. ^1,2 , Ishchenko Arcady V. ^1,2 , Prosvirin Igor P. ² , Sadykov Vladislav A. ^1,2 , Bespalko Yuliya N. ^1,2

Организации

1	Novosibirsk State University, Novosibirsk 630090, Russia
2	Federal Research Center Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia

Информация о финансировании (1)

Российский научный фонд

24-23-20119 (124042300018-9)

Ethanol dry reforming is a promising way to produce syngas and hydrogen due to utilization of carbon dioxide and ability to produce ethanol using renewable sources. Main problem associated with ethanol dry reforming reaction is coke formation. Coking suppression can be achieved in a few ways including use of catalysts possessing required oxygen transport properties. High entropy oxides are of interest in application as catalysts for ethanol dry reforming and other reactions due to their structural stability, disordering features and tunability of functional properties. In this work, the catalysts based on Ni and multiple doped La manganites are studied. The oxides are synthesized by modified Pechini and citrate techniques, and the catalysts are prepared by wetness impregnation. The samples are characterized by XRD, TEM with EDX analysis, XPS. Oxygen transport and redox properties are studied by temperature-programmed isotope exchange of oxygen and reduction. According to structural and morphological studies, the samples are nanosized and form perovskite-like structure. The surface features of samples were characterized by XPS. The samples demonstrate a moderate oxygen mobility (D* up to ∼10–12 cm2/s at 700 °C) required for catalytic operation and coking suppression. Tests in ethanol dry reforming demonstrated fine performance and good stability in the reaction conditions.

Eremeev N.F. , Hanna S.A. , Sadovskaya E.M. , Leonova A.A. , Bulavchenko O.A. , Ishchenko A.V. , Prosvirin I.P. , Sadykov V.A. , Bespalko Y.N.
Catalysts for Ethanol Dry Reforming Based on High-Entropy Perovskites
Journal of Catalysis. 2025. V.445. 116028 :1-31. DOI: 10.1016/j.jcat.2025.116028 WOS Scopus OpenAlex

Поступила в редакцию:	28 окт. 2024 г.
Принята к публикации:	14 февр. 2025 г.
Опубликована online:	17 февр. 2025 г.
Опубликована в печати:	25 мая 2025 г.

Web of science:	WOS:001439960800001
Scopus:	2-s2.0-85219091368
OpenAlex:	W4407631803

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