Catalytic Cracking of n-Dodecane over P-Modified MFI Zeolites Synthesized by Steam-Assisted Conversion: Effect of SiO2/Al2O3 Ratio Full article
| Journal |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
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| Output data | Year: 2024, Volume: 64, Number: 9, Pages: 1096-1105 Pages count : 10 DOI: 10.1134/S0965544124060203 | ||||||
| Tags | zeolites, MFI, ZSM-5, modification with phosphorus, cracking of n-dodecane | ||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Science Foundation | 24-13-00103 (124051600007-2) |
| 2 | Ministry of Science and Higher Education of the Russian Federation | FWUR-2024-0039 |
| 3 | Ministry of Science and Higher Education of the Russian Federation |
Abstract:
The paper describes the physicochemical characterization and catalytic testing of MFI zeolites with different SiO2/Al2O3 ratios synthesized by steam-assisted crystallization (SAC) and modified with phosphorus (4 wt % loading). Their physicochemical properties were characterized by X-ray diffraction analysis, X-ray fluorescence analysis, scanning electron microscopy, low-temperature nitrogen adsorption, ammonia temperature-programmed desorption, and MAS NMR spectroscopy. Both the parent and P-modified MFI zeolites were then subjected to catalytic tests in cracking of n-dodecane. The yield of light olefins was enhanced only in two cases: when MFI zeolites with SiO2/Al2O3 ratios of 30–70 were modified with 4 wt % phosphorus and when parent MFI zeolites with SiO2/Al2O3 ratios of 100–220 were used. It was further found that, in terms of catalytic performance in the cracking of n-dodecane, the MFI zeolites synthesized by SAC were comparable to a commercially available MFI zeolite synthesized under hydrothermal conditions. Moreover, in contrast to the commercially available zeolite, phosphorus modification of the SAC-synthesized zeolite enhanced the yield of C2–C4 olefins.
Cite:
Bachurina D.O.
, Giliazutdinova A.S.
, Potapenko O.V.
, Ivanova I.I.
Catalytic Cracking of n-Dodecane over P-Modified MFI Zeolites Synthesized by Steam-Assisted Conversion: Effect of SiO2/Al2O3 Ratio
Petroleum Chemistry. 2024. V.64. N9. P.1096-1105. DOI: 10.1134/S0965544124060203 WOS Scopus РИНЦ OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Catalytic Cracking of n-Dodecane over P-Modified MFI Zeolites Synthesized by Steam-Assisted Conversion: Effect of SiO2/Al2O3 Ratio
Petroleum Chemistry. 2024. V.64. N9. P.1096-1105. DOI: 10.1134/S0965544124060203 WOS Scopus РИНЦ OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Original:
Бачурина Д.О.
, Гилязутдинова А.С.
, Потапенко О.В.
, Иванова И.И.
Каталитический крекинг н-додекана на цеолитах MFI, полученных методом парофазной кристаллизации и модифицированных фосфором: влияние отношения SiO2/Al2O3
Современные молекулярные сита. 2024. Т.6. №2. С.36-45. DOI: 10.53392/27130304_2024_6_2_36 РИНЦ publication_identifier_short.sciact_ihcp_identifier_type
Каталитический крекинг н-додекана на цеолитах MFI, полученных методом парофазной кристаллизации и модифицированных фосфором: влияние отношения SiO2/Al2O3
Современные молекулярные сита. 2024. Т.6. №2. С.36-45. DOI: 10.53392/27130304_2024_6_2_36 РИНЦ publication_identifier_short.sciact_ihcp_identifier_type
Dates:
| Published print: | Sep 1, 2024 |
| Submitted: | Sep 18, 2024 |
| Accepted: | Oct 28, 2024 |
| Published online: | Dec 19, 2024 |
Identifiers:
| Web of science: | WOS:001379986700001 |
| Scopus: | 2-s2.0-85212418625 |
| Elibrary: | 79026742 |
| OpenAlex: | W4405524732 |
| publication_identifier.sciact_ihcp_identifier_type: | 4431 |
Citing:
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