Effect of surface Fe- and Cu-species on the flat-band potential and photoelectrocatalytic properties of N-doped TiO2 | Sciact - CRIS-система Института катализа

Effect of surface Fe- and Cu-species on the flat-band potential and photoelectrocatalytic properties of N-doped TiO2 Научная публикация

Журнал

Journal of Photochemistry and Photobiology A: Chemistry
ISSN: 1010-6030 , E-ISSN: 1873-2666

Вых. Данные

Год: 2025, Том: 464, Номер статьи : 116342, Страниц : 11 DOI: 10.1016/j.jphotochem.2025.116342

Ключевые слова

Photoelectrocatalysis, N-doped TiO2 (TiO2-N), Metal grafting, Flat-band potential, Action spectrum, Water oxidation reaction, Methanol oxidation reaction

Авторы

Gribov Evgeny ¹ , Koshevoy Evgeny ¹ , Fazliev Timur ¹ , Lyulyukin Mikhail ¹ , Kozlov Denis ¹ , Selishchev Dmitry ¹

Организации

1	Boreskov Institute of Catalysis SB RAS, Lavrentieva Ave. 5, Novosibirsk 630090, Russia

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)

FWUR-2024-0036

Surface modification of N-doped TiO2 photocatalyst with transition metals is regarded as a promising approach to increase its ability in the visible-light driven oxidation of organic compounds. Photoelectrocatalytic characterization of semiconducting materials is useful technique to evaluate the potentials of photogenerated charge carriers for analysis of their transfer and reaction pathways. In this study, the surface of TiO2-N was decorated with iron or copper species by a simple impregnation method. Fe and Cu were selected as efficient surface traps for electrons and holes, respectively. The metal-decorated photocatalysts were studied using a series of (photo)electrochemical methods with/without addition of methanol as a sacrificial agent to evaluate the position of their flat-band potentials and investigate the effect of metals on the action spectrum of TiO2-N in the range of 370–500 nm. Comprehensive analysis revealed that the flat-band potentials of Fe- and Cu-modified photocatalysts are similar (−0.30 ÷ −0.32 V vs. RHE) and slightly negative than the potential of initial TiO2-N (−0.26 V vs. RHE). Furthermore, the modification of TiO2-N with iron and copper species substantially increased visible-light induced photocurrent in both aqueous and methanol-added electrolytes, especially at long wavelengths. The enhanced photoelectrocatalytic activity of metal-decorated photocatalysts was considered in viewpoint of metal effect on the recombination of photogenerated charge carriers and occurring water or methanol oxidation reactions.

Gribov E. , Koshevoy E. , Fazliev T. , Lyulyukin M. , Kozlov D. , Selishchev D.
Effect of surface Fe- and Cu-species on the flat-band potential and photoelectrocatalytic properties of N-doped TiO2
Journal of Photochemistry and Photobiology A: Chemistry. 2025. V.464. 116342 :1-11. DOI: 10.1016/j.jphotochem.2025.116342 WOS Scopus CAPlus OpenAlex

Поступила в редакцию:	16 окт. 2024 г.
Принята к публикации:	12 февр. 2025 г.
Опубликована online:	13 февр. 2025 г.
Опубликована в печати:	1 июл. 2025 г.

Web of science:	WOS:001430410200001
Scopus:	2-s2.0-85217936709
Chemical Abstracts:	2025:411529
OpenAlex:	W4407510355

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