Sub-20-nm Magnetite-Based Core-Shell Nanoparticles with Strong Magnetic, Magnetoelectric, and Nanocatalytic Properties | Sciact - CRIS-система Института катализа

Sub-20-nm Magnetite-Based Core-Shell Nanoparticles with Strong Magnetic, Magnetoelectric, and Nanocatalytic Properties Научная публикация

Журнал

Ceramics International
ISSN: 0272-8842

Вых. Данные

Год: 2025, DOI: 10.1016/j.ceramint.2025.02.331

Ключевые слова

Magnetoelectrics; Core-shell nanoparticles; Magnetite; Ba0.85Ca0.15Zr0.1Ti0.9O3; Nanocatalysis

Авторы

Urakova Alina ¹ , Baksheev Artem ¹ , Praydko Artyom ¹ , Grubova Irina ¹ , Surmeneva Maria ¹ , Chernozem Polina ¹ , Mukhortova Yulia ¹ , Wagner Dmitry ² , Gerasimov Evgeniy ³ , Kazantsev Sergey ⁴ , Lozhkomoev Aleksandr ^1,4 , Lisitsyn Sergey ⁵ , Sukhorukov Gleb ⁶ , Surmenev Roman ¹ , Chernozem Roman ¹

Организации

1	National Research Tomsk Polytechnic University, Tomsk, 634050, Russia
2	National Research Tomsk State University, Tomsk, 634050, Russia
3	Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
4	Institute of Strength Physics and Materials Science, SB RAS, Tomsk, 634055, Russia
5	Life Improvement By Future Technology Center LLC (LIFT), Nobel Str. 5, Moscow, 121205, Russia
6	Vladimir Zelman Center for Neurobiology and Brain Rehabilitation, Moscow, Russia

Информация о финансировании (1)

Российский научный фонд

23-23-00511 (123012000053-7)

Magnetoelectric (ME) nanoparticles (NPs) have garnered much attention of researchers in the field of biomedicine owing to multiferroic properties. Here, novel sub-20-nm ME core–shell NPs—based on biocompatible magnetic Fe3O4 (FO) as a magnetostrictive core and ferroelectric perovskite Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) as a ferroelectric shell—were designed for the first time via in situ microwave-assisted hydrothermal synthesis. Comprehensive characterization confirmed epitaxial growth of the very thin (down to 5 nm) ferroelectric perovskite BCZT shell on the spinel FO core, with an average size of 14.5 ± 4.6 nm (mean ± standard deviation). These sub-20-nm ME FO@BCZT core–shell NPs showed high saturation magnetization (24.8 ± 0.7 emu/g). Furthermore, FO@BCZT NPs manifested robust piezoelectricity (13 ± 3 p.m./V) and a superior ME coefficient (11.9 × 105 mV/[cm∙Oe]), which is comparable to that of potentially toxic Co-based analogs and significantly higher than values reported for larger magnetite-based ME NPs. Notably, ME performance of FO@BCZT NPs was tested and showed 85 % efficiency of degradation of model pollutant Rhodamine 6G after 3 h of treatment with a safe low-intensity alternating magnetic field (150 mT, 100 Hz). Thus, the newly developed ME core–shell FO@BCZT NPs are a promising candidate for diverse applications: from nanocatalysis to targeted drug delivery and cancer therapy.

Urakova A. , Baksheev A. , Praydko A. , Grubova I. , Surmeneva M. , Chernozem P. , Mukhortova Y. , Wagner D. , Gerasimov E. , Kazantsev S. , Lozhkomoev A. , Lisitsyn S. , Sukhorukov G. , Surmenev R. , Chernozem R.
Sub-20-nm Magnetite-Based Core-Shell Nanoparticles with Strong Magnetic, Magnetoelectric, and Nanocatalytic Properties
Ceramics International. 2025. DOI: 10.1016/j.ceramint.2025.02.331 Scopus

Поступила в редакцию:	3 дек. 2024 г.
Принята к публикации:	22 февр. 2025 г.
Опубликована online:	23 февр. 2025 г.

Scopus:

2-s2.0-85219062349

Пока нет цитирований