Effect of sp2-Hybridized Carbon Inclusions in Diamond Films on the Sensor Performance Toward Synchrotron Radiation | Sciact - CRIS-система Института катализа

Effect of sp2-Hybridized Carbon Inclusions in Diamond Films on the Sensor Performance Toward Synchrotron Radiation Научная публикация

Журнал

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Вых. Данные

Год: 2024, Том: 65, Номер: 9, Страницы: 1774-1783 Страниц : 10 DOI: 10.1134/S0022476624090087

Ключевые слова

polycrystalline diamond film, sp2-carbon, Raman scattering, photoconductivity, synchrotron radiation

Авторы

Sedelinikova O.V. ¹ , Gorodetskiy D.V. ¹ , Fedorenko A.D. ^1,2 , Baskakova K.I. ¹ , Paddubskaya A.G. ³ , Korolik O.V. ⁴ , Valynets N.I. ³ , Nikolenko A.D. ^2,5 , Okotrub A.V. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Synchrotron Radiation Facility-Siberian Circular Photon Source “SKlF”, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Koltsovo, Russia
3	Institute for Nuclear Problems of Belarusian State University, Minsk, Belarus
4	Faculty of Physics, Belarusian State University, Minsk, Belarus
5	Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

We present a study of the structural features of polycrystalline a diamond film (PCDF) synthesized by the microwave plasma-enhanced chemical vapor deposition method from a hydrogen/pentane mixture and consider its photoelectric response to synchrotron radiation. Raman spectroscopy analysis of the PCDF cross-section revealed the presence of sp2-hybridized inclusions. As the distance from the PCDF growth surface increases, the amount of the non-diamond phase also increases, while its morphology changes from amorphous to crystalline graphite-like carbon. The investigation of the photoelectric response of PCDF was carried out at the “Cosmos” station using synchrotron radiation from the VEPP-4M storage ring. The PCDF detector exhibited maximum sensitivity at low bias voltage. This effect was attributed to the increased efficiency of collecting photo-induced charge carriers from the diamond to the sp2-hybridized inclusions followed by their subsequent transport through conductive paths along the boundaries between diamond crystallites.

Sedelinikova O.V. , Gorodetskiy D.V. , Fedorenko A.D. , Baskakova K.I. , Paddubskaya A.G. , Korolik O.V. , Valynets N.I. , Nikolenko A.D. , Okotrub A.V.
Effect of sp2-Hybridized Carbon Inclusions in Diamond Films on the Sensor Performance Toward Synchrotron Radiation
Journal of Structural Chemistry. 2024. V.65. N9. P.1774-1783. DOI: 10.1134/S0022476624090087 WOS Scopus СКИФ ID

Седельникова О.В. , Городецкий Д.В. , Федоренко А.Д. , Баскакова К.И. , Поддубская О.Г. , Королик О.В. , Волынец Н.И. , Николенко А.Д. , Окотруб А.В.
Влияние sp2-гибридизированных углеродных включений в алмазной пленке на сенсорные свойства по отношению к синхротронному излучению
Журнал структурной химии. 2024. Т.65. №9. 132222 :1-10. DOI: 10.26902/jsc_id132222 OpenAlex СКИФ ID

Поступила в редакцию:	4 апр. 2024 г.
Принята к публикации:	6 мая 2024 г.
Опубликована в печати:	1 сент. 2024 г.
Опубликована online:	2 окт. 2024 г.

Web of science:	WOS:001329290400001
Scopus:	2-s2.0-85206094275
СКИФ ID:	3827

БД	Цитирований
Scopus	1
Web of science	1