Prospects for Synthesizing Linear Alkylbenzenes via the Homogeneous Catalytic Alkylation of Benzene with Mixtures of Olefins of Complex Composition: Using Two-Dimensional Chromatography to Study the Composition of Products Full article
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Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2025, Volume: 17, Number: 1, Pages: 1-9 Pages count : 9 DOI: 10.1134/s207005042470034x | ||
| Tags | two-dimensional chromatography, benzene alkylation, linear alkylbenzenes, linear alpha olefins, methanesulfonic acid | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 17-73-30032-П |
Abstract:
The catalytic alkylation of benzene with a multicomponent mixture consisting of products from the thermal pyrolysis of higher paraffins and containing a wide fraction of olefins of various structures is studied. Methanesulfonic acid, which has weak corrosion properties compared to industrial catalytic systems, is used as a homogeneous catalyst. Using two-dimensional gas chromatography to analyze the composition of both the initial multicomponent raw material and the products of alkylation allow the selection of the initial process conditions and the correct calculation of such parameters for assessing efficiency as selectivity and conversion. Depending on the raw material, the selectivity to linear alkylbenzene (LAB) is ranged within 82.4–88.3%; for 2-LABs, it is 29.2–41.3% at ~90% olefin conversion.
Cite:
Golub F.S.
, Bolotov V.S.
, Shabalin A.Y.
, Dolgushev P.A.
, Parmon V.N.
Prospects for Synthesizing Linear Alkylbenzenes via the Homogeneous Catalytic Alkylation of Benzene with Mixtures of Olefins of Complex Composition: Using Two-Dimensional Chromatography to Study the Composition of Products
Catalysis in Industry. 2025. V.17. N1. P.1-9. DOI: 10.1134/s207005042470034x WOS Scopus РИНЦ OpenAlex
Prospects for Synthesizing Linear Alkylbenzenes via the Homogeneous Catalytic Alkylation of Benzene with Mixtures of Olefins of Complex Composition: Using Two-Dimensional Chromatography to Study the Composition of Products
Catalysis in Industry. 2025. V.17. N1. P.1-9. DOI: 10.1134/s207005042470034x WOS Scopus РИНЦ OpenAlex
Original:
Голубь Ф.С.
, Болотов В.А.
, Шабалин А.Ю.
, Долгушев П.А.
, Пармон В.Н.
Перспективы синтеза линейных алкилбензолов при гомогенном каталитическом алкилировании бензола смесями олефинов сложного состава: исследование состава продуктов методом двумерной хроматографии
Катализ в промышленности. 2024. Т.24. №3. С.50-59. DOI: 10.18412/1816-0387-2024-3-50-59 РИНЦ AN OpenAlex
Перспективы синтеза линейных алкилбензолов при гомогенном каталитическом алкилировании бензола смесями олефинов сложного состава: исследование состава продуктов методом двумерной хроматографии
Катализ в промышленности. 2024. Т.24. №3. С.50-59. DOI: 10.18412/1816-0387-2024-3-50-59 РИНЦ AN OpenAlex
Dates:
| Submitted: | Nov 15, 2023 |
| Accepted: | Dec 6, 2023 |
| Published print: | Mar 1, 2025 |
Identifiers:
| Web of science: | WOS:001494376100003 |
| Scopus: | 2-s2.0-105006666701 |
| Elibrary: | 82358108 |
| OpenAlex: | W4410696997 |
Citing:
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